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主要文件

228036

Sigma-Aldrich

OXONE®,单过硫酸盐化合物

别名:

单过硫酸氢钾

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50 G
¥3,231.30
250 G
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About This Item

线性分子式:
KHSO5 · 0.5KHSO4 · 0.5K2SO4
CAS号:
分子量:
307.38
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.21

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蒸汽压

<0.0000017 hPa

质量水平

表单

powder

反应适用性

reagent type: oxidant

浓度

>4.0% (active oxygen basis (by Na2S2O3, titration))

pH值(酸碱度)

2.1 (77 °C, 30 g/L)

SMILES字符串

[K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O

InChI

1S/5K.2H2O5S.2H2O4S/c;;;;;2*1-5-6(2,3)4;2*1-5(2,3)4/h;;;;;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5

InChI key

HJKYXKSLRZKNSI-UHFFFAOYSA-I

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一般描述

OXONE®单过硫酸钾氧酮是一种钾三元盐,主要用作稳定、易处理、无毒的氧化剂。[1]

应用

OXONE®单过硫酸盐化合物可作为过渡金属氧化剂的替代品,用于将醛类转化为羧酸或酯类。[1]
据报道,使用缓冲的 OXONE 可以快速有效地从亚胺合成氧氮杂环丙烷。[2]也用于研究美术颜料的褪色。[3]
用于卤化α,β不饱和羰基化合物和催化生成用于酒精氧化的高价碘试剂的氧化剂。

法律信息

OXONE is a registered trademark of E. I. du Pont de Nemours and Company

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

WGK

WGK 3

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

  • 技术规格说明书

  • 历史批次信息供参考:

    分析证书(COA)

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    Yifu Li et al.
    Bioresource technology, 262, 294-301 (2018-05-08)
    In this study, zero valent iron (ZVI) activated peroxymonosulfate (PMS) as novel technique (i.e. ZVI-PMS technology) was employed to enhance sludge dewatering. In optimal sludge dewatering conditions of ZVI and KHSO5 dosages, the specific resistance to filtration (SRF) was reduced
    Jiamin Hu et al.
    Water science and technology : a journal of the International Association on Water Pollution Research, 79(5), 911-920 (2019-04-27)
    In this study, the difference in oxidative capacity for removing antibiotics and the mechanism between the Cu(II)/peroxymonosulfate (PMS)/UV and Cu(II)/persulfate (PDS)/UV systems were compared under various conditions. The optimal Cu(II) concentration in the Cu(II)/PMS/UV system was 30 μM, and in
    Yi-Fong Huang et al.
    Journal of hazardous materials, 167(1-3), 418-426 (2009-02-14)
    This study investigated the degradation and mineralization of Bisphenol A (BPA) at pH 7, taken as a model compound in the presence of the trace metal-ions, Co(2+), and peroxymonosulfate (Oxone: PMS). We took advantage of the high oxidation-reduction potential of
    Benjamin R Travis et al.
    Organic letters, 5(7), 1031-1034 (2003-03-28)
    [reaction: see text] A highly efficient, mild, and simple protocol is presented for the oxidation of aldehydes to carboxylic acids utilizing Oxone as the sole oxidant. Direct conversion of aldehydes in alcoholic solvents to their corresponding ester products is also
    Yao-Hui Huang et al.
    Journal of hazardous materials, 170(2-3), 1110-1118 (2009-06-23)
    In order to generate powerful radicals as oxidizing species for the complete decolorization and degradation of azo dye Reactive Black B (RBB) at near neutral pH (pH 6), homogeneous activation of peroxymonosulfate (Oxone: PMS) by the trace Co2+-catalysts was explored.

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    Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

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