22070
(+)-香芹酮
analytical standard
别名:
(+)-p-薄荷-6,8-二烯 2-酮, (S)-5-异丙烯基-2-甲基-2-环已烯酮
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关于此项目
经验公式（希尔记法）:
C10H14O
化学文摘社编号:
分子量:
150.22
UNSPSC Code:
85151701
NACRES:
NA.24
PubChem Substance ID:
EC Number:
218-827-2
Beilstein/REAXYS Number:
2042970
MDL number:
产品名称
(+)-香芹酮, analytical standard
InChI key
ULDHMXUKGWMISQ-VIFPVBQESA-N
InChI
1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m0/s1
SMILES string
CC(=C)[C@H]1CC=C(C)C(=O)C1
grade
analytical standard
assay
≥98.5% (sum of enantiomers, GC)
optical activity
[α]20/D +61±2°, neat
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable
gas chromatography (GC): suitable
refractive index
n20/D 1.499
bp
228-230 °C (lit.)
density
0.960 g/mL at 20 °C (lit.)
application(s)
agriculture
environmental
food and beverages
format
neat
Quality Level
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General description
（+）-香芹酮（S-香芹酮）是一种单萜，具有影响植物生长发育和微生物活性调节的能力，它还可以通过抑制苯丙氨酸氨裂合酶（PAL）的诱导来防止马铃薯发芽。
Other Notes
该化合物常见于葛缕子属、薄荷属、姜属植物
signalword
Warning
hcodes
Hazard Classifications
Skin Sens. 1A
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
204.1 °F - closed cup
flash_point_c
95.6 °C - closed cup
ppe
Eyeshields, Gloves
Possible regulatory role of phenylalanine ammonia?lyase in the production of anthocyanins in asparagus (Asparagus officinalis L).
Flores, Francisco B., et al.
Journal of the Science of Food and Agriculture, 85.6, 925-930 (2005)
Haishen Yang et al.
Organic letters, 13(14), 3670-3673 (2011-06-17)
A highly efficient route was developed to synthesize (-)-8-epigrosheimin in four steps from aldehyde 2 based on a substrate-controlled method. The key steps of the synthesis included (1) a stereo- and regioselective allylation addition, (2) an intramolecular translactonization, and (3)
Mengyang Xuan et al.
Organic letters, 14(21), 5492-5495 (2012-10-26)
The total synthesis of the cAMP signaling pathway activator (-)-alotaketal A is reported. A convergent approach to the unusual alotane sesterterpenoid skeleton was employed, exploiting a remarkable LiDBB-mediated coupling of an (R)-carvone-derived δ-lactone with an allyl bromide side chain, followed
Hee Jin Kim et al.
Organic letters, 13(10), 2682-2685 (2011-04-23)
Selective deoxygenation of allylic alcohol can be successfully carried out by the formation of alkoxyalkyl ether (EE or MOM), followed by Pd(dppe)Cl(2)-catalyzed reduction with LiBHEt(3). (+)-S-Lavandulol has been efficiently synthesized by the application of this protocol to the diol derived
Marta Goretti et al.
Bioresource technology, 121, 290-297 (2012-08-04)
Response surface methodology was applied in optimizing the asymmetric bioreduction of (4S)-(+)-carvone to dihydrocarvone (with low incidence of unsought side reactions) by using whole-cells of Cryptococcus gastricus. A factorial design (2(5)) including five independent variables was performed: X(1)=incubation time; X(2)=pH;
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