21360
(+)-樟脑-10-磺酸
purum, ≥98.0% (T)
别名:
(+)-β-樟脑磺酸, (1S)-(+)-樟脑-10-磺酸
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关于此项目
经验公式（希尔记法）:
C10H16O4S
化学文摘社编号:
分子量:
232.30
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-554-1
Beilstein/REAXYS Number:
2809675
MDL number:
产品名称
(+)-樟脑-10-磺酸, purum, ≥98.0% (T)
InChI key
MIOPJNTWMNEORI-GMSGAONNSA-N
InChI
1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1
SMILES string
[H][C@@]12CC[C@@](CS(O)(=O)=O)(C(=O)C1)C2(C)C
grade
purum
assay
≥98.0% (T)
form
solid
optical activity
[α]20/D +21.5±1°, c = 10% in H2O
mp
~200 °C (dec.) (lit.)
functional group
ketone
sulfonic acid
Quality Level
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Application
（+） -樟脑-10-磺酸可作为合成10-碘樟脑的起始原料。(±)-S-甲基-S-苯基磺酰亚胺可作为手性拆分剂进行拆分，形成具有较高对映体纯度的 (-)-形式。掺杂 (+)-樟脑-10-磺酸的聚苯胺 (PAni) 形成导电聚合物纳米纤维，是优良的氨气传感器。
Other Notes
用于拆分碱的试剂；也可作为液相色谱分离的流动相添加剂；用于结晶诱导的不对称转化的试剂
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
A. Lore et al.
Journal of Liquid Chromatography, 14, 2065-2065 (1991)
P.J. Reider et al.
The Journal of Organic Chemistry, 52, 955-955 (1987)
T. Shiraiwa et al.
Bulletin of the Chemical Society of Japan, 64, 3729-3729 (1991)
Electrospun polyaniline fibers as highly sensitive room temperature chemiresistive sensors for ammonia and nitrogen dioxide gases.
Zhang Y, et al.
Advances in Functional Materials, 24(25), 4005-4014 (2014)
C Pettersson et al.
Journal of chromatography, 204, 179-183 (1981-01-16)
A high-performance liquid chromatographic method for the separation of optical isomers (enantiomers) of amines is described. It is based on ion-pair chromatography with a chiral counter ion in a system with an organic mobile phase and an adsorbing stationary phase.
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