等级
purum p.a.
质量水平
检测方案
≥98.0% (T)
缺失
≤2% loss on drying
mp
610 °C (dec.) (lit.)
痕量阴离子
chloride (Cl-): ≤1000 mg/kg
sulfate (SO42-): ≤500 mg/kg
痕量阳离子
Ca: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤200 mg/kg
Na: ≤250 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg
SMILES字符串
[Cs+].[Cs+].[O-]C([O-])=O
InChI
1S/CH2O3.2Cs/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2
InChI key
FJDQFPXHSGXQBY-UHFFFAOYSA-L
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应用
Catalyst for:
aerobic oxidation of primary alcohols
1,4-addition reactions
Reagent for:
Synthesis of phosphazene derivatives
Constrictive binding interactions
Intramolecular C-N cross coupling reactions
Dehydrohalogenative polycondensation
aerobic oxidation of primary alcohols
1,4-addition reactions
Reagent for:
Synthesis of phosphazene derivatives
Constrictive binding interactions
Intramolecular C-N cross coupling reactions
Dehydrohalogenative polycondensation
提高醇 O-烷基化的效率以生成碳酸烷基酯混合物。
其他说明
用于制备与卤化物反应生成酯和内酯的羧酸铯;用于硫醚的类似制备
警示用语:
Danger
危险声明
危险分类
Eye Dam. 1 - Repr. 2 - STOT RE 2 Oral
靶器官
Kidney,Adrenal gland,Testes
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Journal of the American Chemical Society, 103, 5183-5183 (1981)
Synthetic Communications, 13, 553-553 (1983)
Inorgorganica Chimica Acta, 363, 3721-3726 (2010)
Advanced Synthesis & Catalysis, 351, 3150-3156 (2009)
Tetrahedron Letters, 51, 3956-3959 (2010)
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