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等级
technical
质量水平
方案
≥90% (GC)
表单
liquid
杂质
≤8% tert-butyl alcohol
折射率
n20/D 1.368 (lit.)
n20/D 1.368
沸点
61-63 °C (lit.)
溶解性
alcohol: very soluble
chloroform: very soluble
diethyl ether: very soluble
glycerol: insoluble
water: slightly soluble
密度
0.864 g/mL at 20 °C
0.867 g/mL at 25 °C (lit.)
官能团
O-nitroso
nitroso
储存温度
2-8°C
SMILES字符串
CC(C)(C)ON=O
InChI
1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3
InChI key
IOGXOCVLYRDXLW-UHFFFAOYSA-N
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一般描述
亚硝酸盐叔丁基是一种有机构件，广泛应用于各种有机转化，如氧化、重氮化、亚硝化、硝化、氧化、N-合成单体和其他反应。
应用
亚硝基叔丁酯可作为重氮合成芳基重氮盐的反应物。
其他说明
用于亚硝化、动力学反应的试剂；近紫外光解生成 Me3C 自由基的清洁来源
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
14.0 °F - closed cup
闪点(°C)
-10 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
Quantum defects as versatile anchors for carbon nanotube functionalization
Mann F, et al.
Nature Protocols, 17, 727-747 (2022)
L. Batt et al.
International Journal of Chemical Kinetics, 21, 535-535 (1989)
tert-Butyl Nitrite (TBN), a Multitasking Reagent in Organic Synthesis
Dahiya A, et al.
Chemistry - An Asian Journal, 14, 4454-4492 (2019)
M.J. Crookes et al.
J. Chem. Soc. Perkin Trans. II, 1339-1339 (1988)
Brenden Kilpatrick et al.
Chemical communications (Cambridge, England), 49(5), 514-516 (2012-12-01)
A methodology for the efficient conversion of aromatic sulfonamides into their mono-nitro derivatives using tert-butyl nitrite is reported. The reaction exhibits a high degree of chemoselectivity for sulfonamide functionalized aryl systems, even in the presence of other sensitive or potentially
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