20370
亚硝酸叔丁酯
technical, ≥90% (GC)
别名:
1,1-Dimethylethyl nitrite
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关于此项目
线性分子式:
(CH3)3CONO
化学文摘社编号:
分子量:
103.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-757-0
Beilstein/REAXYS Number:
1209339
MDL number:
产品名称
亚硝酸叔丁酯, technical, ≥90% (GC)
InChI key
IOGXOCVLYRDXLW-UHFFFAOYSA-N
InChI
1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3
SMILES string
CC(C)(C)ON=O
grade
technical
assay
≥90% (GC)
form
liquid
impurities
≤8% tert-butyl alcohol
refractive index
n20/D 1.368 (lit.)
n20/D 1.368
bp
61-63 °C (lit.)
solubility
alcohol: very soluble
chloroform: very soluble
diethyl ether: very soluble
glycerol: insoluble
water: slightly soluble
density
0.864 g/mL at 20 °C
0.867 g/mL at 25 °C (lit.)
functional group
O-nitroso
nitroso
storage temp.
2-8°C
Quality Level
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Application
亚硝基叔丁酯可作为重氮合成芳基重氮盐的反应物。
General description
亚硝酸盐叔丁基是一种有机构件，广泛应用于各种有机转化，如氧化、重氮化、亚硝化、硝化、氧化、N-合成单体和其他反应。
Other Notes
用于亚硝化、动力学反应的试剂；近紫外光解生成 Me3C 自由基的清洁来源
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
14.0 °F - closed cup
flash_point_c
-10 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
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Mann F, et al.
Nature Protocols, 17, 727-747 (2022)
L. Batt et al.
International Journal of Chemical Kinetics, 21, 535-535 (1989)
Brenden Kilpatrick et al.
Chemical communications (Cambridge, England), 49(5), 514-516 (2012-12-01)
A methodology for the efficient conversion of aromatic sulfonamides into their mono-nitro derivatives using tert-butyl nitrite is reported. The reaction exhibits a high degree of chemoselectivity for sulfonamide functionalized aryl systems, even in the presence of other sensitive or potentially
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