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等级
technical
质量水平
检测方案
≥90% (GC)
形式
liquid
杂质
≤8% tert-butyl alcohol
折射率
n20/D 1.368 (lit.)
n20/D 1.368
bp
61-63 °C (lit.)
溶解性
alcohol: very soluble
chloroform: very soluble
diethyl ether: very soluble
glycerol: insoluble
water: slightly soluble
密度
0.864 g/mL at 20 °C
0.867 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC(C)(C)ON=O
InChI
1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3
InChI key
IOGXOCVLYRDXLW-UHFFFAOYSA-N
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一般描述
亚硝酸盐叔丁基是一种有机构件，广泛应用于各种有机转化，如氧化、重氮化、亚硝化、硝化、氧化、N-合成单体和其他反应。
应用
亚硝基叔丁酯可作为重氮合成芳基重氮盐的反应物。
其他说明
用于亚硝化、动力学反应的试剂；近紫外光解生成 Me3C 自由基的清洁来源
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
WGK
WGK 1
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
L. Batt et al.
International Journal of Chemical Kinetics, 21, 535-535 (1989)
M.J. Crookes et al.
J. Chem. Soc. Perkin Trans. II, 1339-1339 (1988)
tert-Butyl Nitrite (TBN), a Multitasking Reagent in Organic Synthesis
Dahiya A, et al.
Chemistry - An Asian Journal, 14, 4454-4492 (2019)
Brenden Kilpatrick et al.
Chemical communications (Cambridge, England), 49(5), 514-516 (2012-12-01)
A methodology for the efficient conversion of aromatic sulfonamides into their mono-nitro derivatives using tert-butyl nitrite is reported. The reaction exhibits a high degree of chemoselectivity for sulfonamide functionalized aryl systems, even in the presence of other sensitive or potentially
Quantum defects as versatile anchors for carbon nanotube functionalization
Mann F, et al.
Nature Protocols, 17, 727-747 (2022)
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