等级
purum
质量水平
检测方案
≥98.0% (GC)
折射率
n20/D 1.421 (lit.)
n20/D 1.422
bp
112-114 °C (lit.)
密度
0.838 g/mL at 25 °C (lit.)
SMILES字符串
OCCC=C
InChI
1S/C4H8O/c1-2-3-4-5/h2,5H,1,3-4H2
InChI key
ZSPTYLOMNJNZNG-UHFFFAOYSA-N
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应用
3-Buten-1-ol was used as a starting reagent in asymmetric total synthesis of natural seimatopolide B. It was also used in the synthesis of catalytic bimetallic nanoparticles.
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产品编号
说明
价格
警示用语:
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Biologically programmed synthesis of bimetallic nanostructures.
Advanced Materials, 18(15), 1988-1992 (2006)
Alternating copolymers of functional alkenes with carbon monoxide.
Macromolecules, 29(18), 5852-5858 (1996)
Organic & biomolecular chemistry, 11(20), 3355-3364 (2013-04-09)
The asymmetric total synthesis of natural seimatopolide B along with its enantiomer is described starting from readily available 5-hexen-1-ol and 3-buten-1-ol. The key steps involved are Jacobson hydrolytic kinetic resolution, proline-catalyzed α-hydroxylation, Yamaguchi esterification and ring-closing metathesis. This asymmetric total
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