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Merck
CN

17281

Supelco

五氟丙酰咪唑

for GC derivatization, ≥98.5%

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别名:
1-(全氟丙酰)咪唑
经验公式(希尔记法):
C6H3F5N2O
CAS号:
分子量:
214.09
EC 号:
MDL编号:
UNSPSC代码:
41116105
PubChem化学物质编号:
NACRES:
NA.22

等级

for GC derivatization

质量水平

检测方案

≥98.5% (GC)
≥98.5%

反应适用性

reagent type: derivatization reagent
reaction type: Esterifications

技术

GC/MS: suitable

折射率

n20/D 1.399

密度

1.4 g/mL at 20 °C (lit.)

储存温度

−20°C

SMILES字符串

FC(F)(F)C(F)(F)C(=O)n1ccnc1

InChI

1S/C6H3F5N2O/c7-5(8,6(9,10)11)4(14)13-2-1-12-3-13/h1-3H

InChI key

VZUSRIIEPFQBNE-UHFFFAOYSA-N

一般描述

Derivatization before a GC analysis helps in yielding distinctive products, which can be achieved using a derivatizing reagent that reacts with amino and hydroxyl functionalities quantitatively. 1-(Pentafluoropropionyl)imidazole (PFPI) is a derivatizing reagent which was found to give high yield of products than pentafluoropropionic anhydride during preparation of methyl ester/pentafluoropropionyl derivatives.

应用

PFPI may be used to incubate the lyophilized samples, for derivatization during GC/MS analysis to measure total d-chiro-Inositol content absorbed by rodents.

其他说明

气相色谱中醇和羧酸等物质的衍生化试剂
Reagent for methyl ester, pentafluoropropionyl.

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Skin Corr. 1B

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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J.T. Etse et al.
Journal of Natural Products, 51, 314-314 (1988)
F. Karoum et al.
Biomedical Mass Spectrometry, 2, 183-183 (1975)
D.R. Knapp
Handbook of Analytical Derivatization Reactions, 208-208 (1979)
F Karoum et al.
British journal of pharmacology, 56(4), 403-411 (1976-04-01)
1 Mass fragmentography was used to measure whole brain concentrations of some of the major metabolites of tyramine, octopamine, dopamine and noradrenaline in acutely treated and in ethanol-dependent rats. 2 Treatments with ethanol, either acutely or chronically, failed to alter
Determination of ethanol- and isopropanolamines in air at parts-per-billion levels.
P W Langvardt et al.
Analytical chemistry, 52(4), 669-671 (1980-04-01)

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