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Merck
CN
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安全信息

16898

Supelco

次乌头碱

analytical standard

别名:

16,16-trimethoxy-4-(methoxymethyl)-20-methyl-,8-acetate benzoate,(1-α,6-α,14-α,15-α,16-β)-aconitane-8,13,14,15-tetraol

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About This Item

经验公式（希尔记法）:
C33H45NO10
CAS号:
6900-87-4
分子量:
615.71
UNSPSC代码:
12352200
NACRES:
NA.24

等级

analytical standard

方案

≥97.5% (HPLC)

旋光性

[α]/D 22.5±2.5°, c = 0.1 in chloroform

保质期

limited shelf life, expiry date on the label

包装形式

neat

储存温度

2-8°C

SMILES字符串

O=C(C1=CC=CC=C1)O[C@H]2[C@@]3(O)[C@@H](OC)[C@H](O)[C@]4(OC(C)=O)C5[C@H](OC)C6C([C@@H](OC)CC[C@]6(CN7C)COC)(C75)[C@H](C3)C42

InChI

1S/C33H45NO10/c1-17(35)44-33-21-19(14-31(38,28(42-6)26(33)36)27(21)43-29(37)18-10-8-7-9-11-18)32-20(40-4)12-13-30(16-39-3)15-34(2)25(32)22(33)23(41-5)24(30)32/h7-11,19-28,36,38H,12-16H2,1-6H3/t19-,20+,21?,22?,23+,24?,25?,26+,27-,28+,30+,31-,32?,33-/m1/s1

InChI key

FIDOCHXHMJHKRW-XCIBRDTCSA-N

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一般描述

Hypaconitine is a constituent of diester-diterpene Aconitum alkaloids (AAs), which are found in aconite plants.

应用

Hypaconitine may be used as an analytical standard for the determination of the analyte in biological samples, Aconitum tubers by liquid chromatography (LC) based techniques.

象形图

Skull and crossbones
GHS06

警示用语：

Danger

危险声明

H300 + H330

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

监管及禁止进口产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCBZ6608
BCBW6149
BCBR8710

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Simultaneous analysis of aconitine, mesaconitine, hypaconitine, and jesaconitine in whole blood by LC-MS-MS using a new polymer column
Hattori H, et al.
Forensic Toxicology, 27(1), 7-11 (2009)
Lei-ping He et al.
Journal of analytical toxicology, 33(9), 588-594 (2009-12-31)
A rapid, sensitive, and specific liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS-MS) method was developed and validated for simultaneous determination of aconitine (AC), mesaconitine (MA), and hypaconitine (HA), the three toxic constituents from Sini decoction (SND) in rat plasma. After the
Simultaneous quantitation of aconitine, mesaconitine, hypaconitine, benzoylaconine, benzoylmesaconine and benzoylhypaconine in human plasma by liquid chromatography-tandem mass spectrometry and pharmacokinetics evaluation of ?SHEN-FU? injectable powder
Zhang F, et al.
Journal of Chromatography. B, Biomedical Applications, 873(2), 173-179 (2008)
Bo Sun et al.
Analytical biochemistry, 395(2), 125-133 (2009-08-18)
The Aconitum alkaloids aconitine, mesaconitine, and hypaconitine are the main toxic components in a commonly used traditional Chinese herbal medicine Fu Zi. To provide guidelines for the safe use of this medicine, metabolic changes in Wistar rats caused by these
Ying Xie et al.
Journal of chromatography. A, 1093(1-2), 195-203 (2005-10-20)
By optimizing the extraction, separation and analytical conditions, a reliable and accurate high-performance liquid chromatography (HPLC) method coupled with photodiode array detector (DAD) was developed for simultaneous quantitative determination of six Aconitum alkaloids, i.e., aconitine, mesaconitine, hypaconitine, benzoylaconine, benzoylmesaconine and
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