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一般描述
甲醇钠是一种钠醇盐。铜催化剂存在下,研究了不同反应条件下和非活性芳基溴化物反应。在DMF(二甲基甲酰胺)钯催化剂存在情况下,它能和卤代芳烃反应生成芳烃。
应用
甲醇钠可以用来制备5-(3-叠氮基丙基)尿苷。它还可以用来合成甲基2-氰基-lup-3-羟基-2-en-28-酯(CN-BA),是桦木酸(BA)的一种2-氰基衍生物。
甲醇钠可用作酯交换反应从植物油中获得脂肪酸甲酯(生物柴油)产物的碱催化剂。
警示用语:
Danger
危险分类
Acute Tox. 4 Oral - Flam. Sol. 1 - Met. Corr. 1 - Self-heat. 1 - Skin Corr. 1A
补充剂危害
WGK
WGK 2
闪点(°F)
91.4 °F
闪点(°C)
33 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
监管及禁止进口产品
Production of biodiesel through optimized alkaline-catalyzed transesterification of rapeseed oil.
Fuel: The Science and Technology of Fuel and Energy, 87(3), 265-273 (2008)
Palladium hydrides in organic synthesis. Reduction of aryl halides by sodium methoxide catalyzed by tetrakis (triphenylphosphine) palladium.
The Journal of Organic Chemistry, 43(8), 1619-1620 (1978)
The copper catalysed reaction of sodium methoxide with aryl bromides. A mechanistic study leading to a facile synthesis of anisole derivatives.
Tetrahedron, 45(17), 5565-5578 (1989)
Nature protocols, 7(6), 1097-1112 (2012-05-12)
This protocol describes the detailed experimental procedure for the synthesis of an azide-modified uridine triphosphate analog and its effective incorporation into an oligoribonucleotide by in vitro transcription reactions. Furthermore, procedures for labeling azide-modified oligoribonucleotides post-transcriptionally with biophysical probes by copper(I)-catalyzed
Journal of dairy science, 102(9), 7723-7733 (2019-07-01)
Milk fat adulteration is a common issue in Central Asia. To assess the current situation in the commercial milk market, 17 milk samples were checked for fatty acid (FA) and sterol profiles to detect potential adulteration using multivariate analysis. Analysis
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