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Merck
CN

160997

5,10,15,20-四苯基-21 H ,23 H -卟吩

97%

别名:

内消旋 -四苯基卟啉, 四苯基卟啉

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关于此项目

经验公式(希尔记法):
C44H30N4
化学文摘社编号:
分子量:
614.74
UNSPSC Code:
12171500
NACRES:
NA.47
PubChem Substance ID:
EC Number:
213-025-9
Beilstein/REAXYS Number:
379542
MDL number:
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InChI key

YNHJECZULSZAQK-LWQDQPMZSA-N

InChI

1S/C44H30N4/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36/h1-28,45,48H/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

SMILES string

c1ccc(cc1)-c2c3ccc(n3)c(-c4ccccc4)c5ccc([nH]5)c(-c6ccccc6)c7ccc(n7)c(-c8ccccc8)c9ccc2[nH]9

assay

97%

form

powder or crystals

technique(s)

titration: suitable

impurities

1-3% corresponding chlorin

mp

>300 °C (lit.)

solubility

chloroform: 1 mg/mL, clear to opaque

λmax

514 nm

ε (extinction coefficient)

≥3500 at 480-486 nm in toluene, ≥4000 at 647-653 nm in toluene, ≥5000 at 589-595  nm in toluene, ≥8000 at 546-552 nm in toluene

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

Quality Level

Gene Information

human ... TERT(7015)

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General description

5,10,15,20-四苯基-21H,23H-卟吩是一种卟啉化合物。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

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G S S Saini et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 61(13-14), 3070-3076 (2005-09-17)
We present here the infrared absorption spectra of free-base tetraphenylporphine and its dication. Most of the allowed IR bands of porphyrin skeletal are observed in pairs due to two-fold symmetry of the free-base tetraphenylporphine. Observation of some new bands, disappearance
Pradip Chandra Mandal et al.
Journal of hazardous materials, 187(1-3), 600-603 (2011-02-09)
Reactions of nickel-5,10,15,20-tetraphenylporphine (Ni-TPP) were studied in supercritical water in the presence of toluene without the addition of any catalyst, H(2) or H(2)S that is called a green process. The objective of this study was to remove nickel from Ni-TPP
Elena V Basiuk et al.
Journal of nanoscience and nanotechnology, 7(4-5), 1530-1538 (2007-04-25)
Noncovalent functionalization of carbon nanotubes with meso-tetraphenylporphine (H2TPP) and its metal(II) complexes NiTPP and CoTPP was studied by means of different experimental techniques and theoretical calculations. As follows from the experimental adsorption curves, free H2TPP ligand exhibits the strongest adsorption
Stefan Müllegger et al.
ACS nano, 5(8), 6480-6486 (2011-07-09)
Supporting functional molecules on crystal facets is an established technique in nanotechnology. To preserve the original activity of ionic metallorganic agents on a supporting template, conservation of the charge and oxidation state of the active center is indispensable. We present
G S S Saini
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 64(4), 981-986 (2006-02-07)
Resonance Raman spectra of free-base tetraphenylporphine and its dication obtained with 441.6, 476.5, 488.0 and 514.5 nm excitation lines in the frequency region 100-1625 cm(-1) are reported. Some bands due to in-plane and out-of-plane vibrational modes, which are symmetry forbidden

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