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Merck
CN

158429

二碘甲烷

99%, liquid, ReagentPlus®, contains copper as stabilizer

别名:

碘化亚甲基

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关于此项目

经验公式(希尔记法):
CH2I2
化学文摘社编号:
分子量:
267.84
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
200-841-5
MDL number:
Beilstein/REAXYS Number:
1696892
Assay:
99%
Form:
liquid
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产品名称

二碘甲烷, ReagentPlus®, 99%, contains copper as stabilizer

InChI key

NZZFYRREKKOMAT-UHFFFAOYSA-N

InChI

1S/CH2I2/c2-1-3/h1H2

SMILES string

ICI

vapor density

9.25 (vs air)

product line

ReagentPlus®

assay

99%

form

liquid

contains

copper as stabilizer

bp

67-69 °C/11 mmHg (lit.)

mp

5-8 °C (lit.)

density

3.325 g/mL at 25 °C (lit.)

functional group

iodo

Quality Level

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Application

二碘甲烷可用作接触角测量中的探针溶剂,以分析聚合物表面的亲水性。
二碘甲烷已被用作探针液,用于评价儿茶酚胺涂覆的纤维表面的表面能的极性和分散组分。它可用于制备环丙基酮、酯和酰胺。

General description

二碘甲烷是一种溶剂,可用作形成金属卤化物的卤键供体。

二碘甲烷(CH2I2)是一种含碘的有机化合物。 通过在310nm处光引发,它在乙腈中的分解已有研究。通过飞秒泵浦探针光谱和从头分子动力学模拟对CH2I2的光分解研究表明,该过程可产生二碘甲烷的异构体(CH2I-I)作为热光产物。在大气中,它可在臭氧存在下进行光解,并产生碘氧化物(IO),该过程会导致形成气溶胶。其真空紫外(VUV)光吸收光谱已有报道。

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Nowsheen Goonoo et al.
Materials science & engineering. C, Materials for biological applications, 76, 13-24 (2017-05-10)
In this paper, the biomineralization potential and cellular response of novel blend films of the anionic sulfated polysaccharides kappa-carrageenan (KCG) and fucoidan (FUC) derived from seaweeds with semi-crystalline polyhydroxybutyrate (PHB) and polyhydroxybutyrate-co-valerate (PHBV), respectively, were analyzed. The incorporation of KCG
Anuvab Mandal et al.
The Journal of chemical physics, 140(19), 194312-194312 (2014-05-24)
The electronic absorption spectrum of diiodomethane in the 30,000-95,000 cm(-1) region is investigated using synchrotron radiation; the spectrum in the 50,000-66,500 cm(-1) region is reported for the first time. The absorption bands in the 30,000-50,000 cm(-1) region are attributed to
Michael Odelius et al.
The Journal of chemical physics, 121(5), 2208-2214 (2004-07-21)
Photodissociation of diiodomethane (CH2I2) in acetonitrile solution has been studied with ab initio molecular dynamics simulations, which show how the iso-diiodomethane photoproduct (CH2I-I) can be formed. The first excited state, described by the "restricted open-shell Kohn-Sham" density functional method, is
Solvent-and catalysts-free immobilization of tannic acid and polyvinylpyrrolidone onto PMMA surface by DBD plasma.
Klebert S, et al.
Plasma Processes and Polymers (2017)
Diiodomethane as a halogen bond donor toward metal-bound halides
Alexander N S et al.
CrystEngComm, 19, 2517-2525 (2017)

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