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Merck
CN

157775

Sigma-Aldrich

五氯化磷

reagent grade, 95%

别名:

氯化磷(V)

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About This Item

线性分子式:
PCl5
CAS号:
分子量:
208.24
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.21
方案:
95%
等级:
reagent grade
表单:
powder

等级

reagent grade

质量水平

蒸汽压

<1 mmHg ( 20 °C)

方案

95%

表单

powder

pH值(酸碱度)

1 (5 g/L)

mp

179-181 °C (subl.) (lit.)

SMILES字符串

ClP(Cl)(Cl)(Cl)Cl

InChI

1S/Cl5P/c1-6(2,3,4)5

InChI key

UHZYTMXLRWXGPK-UHFFFAOYSA-N

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一般描述

Phosphorus pentachloride is a light yellow colored phosphorous halide. It participates in the synthesis of thiazoline analogs.

应用

Phosphorus pentachloride may be used in the synthesis of following compounds:
  • benzenesulfonyl chloride
  • malonic dinitrile
  • aromatic sulfonyl chlorides

Phosphorus pentachloride may be used as halogenating reagent to convert any substituted aldehyde into the corresponding vinyl halide. It can also undergo reaction with ammonium chloride to yield linear phosphazenes and cyclophosphazenes.

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Inhalation

靶器官

Respiratory Tract

补充剂危害

储存分类代码

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Ley.VS et al.
Comprehensive Organic Functional Group Transformations: Synthesis: carbon with two heteroatoms, each attached by a single bond (2005)
Allcock H
Phosphorus-Nitrogen Compounds: Cyclic, Linear, and High Polymeric Systems (2012)
Ley.VS
Comprehensive Organic Functional Group Transformations II, 2 (1995)
Synthetic studies of thiazoline and thiazolidine-containing natural products-1. Phosphorus pentachloride-mediated thiazoline construction reaction.
Ino A and Murabayashi A.
Tetrahedron, 55(34), 10271-10282 (1999)
Eagleson M.
Concise Encyclopedia Chemistry, 120-120 (1994)

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