157775
五氯化磷
reagent grade, 95%
别名:
氯化磷(V)
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关于此项目
线性分子式:
PCl5
化学文摘社编号:
分子量:
208.24
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
233-060-3
MDL number:
Assay:
95%
Grade:
reagent grade
Form:
powder
产品名称
五氯化磷, reagent grade, 95%
InChI key
UHZYTMXLRWXGPK-UHFFFAOYSA-N
InChI
1S/Cl5P/c1-6(2,3,4)5
SMILES string
ClP(Cl)(Cl)(Cl)Cl
grade
reagent grade
vapor pressure
<1 mmHg ( 20 °C)
assay
95%
form
powder
pH
1 (5 g/L)
mp
179-181 °C (subl.) (lit.)
Quality Level
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Application
Phosphorus pentachloride may be used in the synthesis of following compounds:
Phosphorus pentachloride may be used as halogenating reagent to convert any substituted aldehyde into the corresponding vinyl halide. It can also undergo reaction with ammonium chloride to yield linear phosphazenes and cyclophosphazenes.
- benzenesulfonyl chloride
- malonic dinitrile
- aromatic sulfonyl chlorides
Phosphorus pentachloride may be used as halogenating reagent to convert any substituted aldehyde into the corresponding vinyl halide. It can also undergo reaction with ammonium chloride to yield linear phosphazenes and cyclophosphazenes.
General description
Phosphorus pentachloride is a light yellow colored phosphorous halide. It participates in the synthesis of thiazoline analogs.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Inhalation
target_organs
Respiratory Tract
supp_hazards
存储类别
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 1
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Ley.VS
Comprehensive Organic Functional Group Transformations II, 2 (1995)
Allcock H
Phosphorus-Nitrogen Compounds: Cyclic, Linear, and High Polymeric Systems (2012)
Ley.VS et al.
Comprehensive Organic Functional Group Transformations: Synthesis: carbon with two heteroatoms, each attached by a single bond (2005)
Eagleson M.
Concise Encyclopedia Chemistry, 120-120 (1994)
Synthetic studies of thiazoline and thiazolidine-containing natural products-1. Phosphorus pentachloride-mediated thiazoline construction reaction.
Ino A and Murabayashi A.
Tetrahedron, 55(34), 10271-10282 (1999)
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