蒸汽密度
4.7 (vs air)
质量水平
蒸汽压
100 mmHg ( 17.8 °C)
105 mmHg ( 20 °C)
检测方案
97%
形式
liquid
折射率
n20/D 1.443 (lit.)
bp
68-70 °C (lit.)
mp
−54 °C (lit.)
密度
1.665 g/mL at 20 °C (lit.)
SMILES字符串
ClS(Cl)(=O)=O
InChI
1S/Cl2O2S/c1-5(2,3)4
InChI key
YBBRCQOCSYXUOC-UHFFFAOYSA-N
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一般描述
磺酰氯是一种含硫试剂。它广泛用于各种化合物的氯化，因为它在反应过程中分解成二氧化硫和氯。因此，它作为各种芳族氯化反应的分子氯来源。人们对其与二甲硫的氯化反应进行了研究。磺酰氯可用作苯酚的对氯氯化反应的有效试剂。
应用
磺酰氯（SO2Cl2）可用于以下研究：
磺酰氯可用作苯酚的对氯氯化反应的有效试剂。
- α-氯酮的合成。
- 酚的特定选择（邻位选择）氯化。
- 单环烯丙基顺式-1,2-二醇转化为相应的反式-1,2-氯代醇。
- β-氯四氢呋喃衍生物的制备。
磺酰氯可用作苯酚的对氯氯化反应的有效试剂。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 2 Inhalation - Eye Dam. 1 - Skin Corr. 1C - STOT SE 3
靶器官
Respiratory system
补充剂危害
WGK
WGK 1
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
Noam I Saper et al.
The Journal of organic chemistry, 79(2), 809-813 (2013-12-18)
2,2,6,6-Tetramethylpiperidine (TMP)-catalyzed (1-10%) chlorinations of phenols by SO2Cl2 in aromatic solvents are more ortho selective than with primary and less hindered secondary amine catalysts. Ortho-selective chlorination is successful even with electron deficient phenols such as 2-hydroxybenzaldehyde and 2'-hydroxyacetophenone. Notably, ortho
Application of Sulfuryl Chloride for the Quick Construction of β-Chlorotetrahydrofuran Derivatives from Homoallylic Alcohols under Mild Conditions.
Zeng X, et al.
Synthesis, 45(17), 2391-2396 (2013)
The chlorination of active hydrogen compounds with sulfuryl chloride. I. Ketones.
Wyman DP and Kaufman PR.
The Journal of Organic Chemistry, 29(7), 1956-1960 (1964)
Chlorinations with sulfuryl chloride. I. The peroxide-catalyzed chlorination of hydrocarbons.
Kharasch MS and Brown HC.
Journal of the American Chemical Society, 61(8), 2142-2150 (1939)
Derek R Boyd et al.
Organic & biomolecular chemistry, 12(13), 2128-2136 (2014-02-27)
Monocyclic allylic cis-1,2-diols reacted with sulfuryl chloride at 0 °C in a regio- and stereo-selective manner to give 2-chloro-1-sulfochloridates, which were hydrolysed to yield the corresponding trans-1,2-chlorohydrins. At -78 °C, with very slow addition of sulfuryl chloride, cyclic sulfates were
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