150495
亚硝酸异戊酯
96%
别名:
亚硝戊酯
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关于此项目
线性分子式:
(CH3)2CHCH2CH2ONO
化学文摘社编号:
分子量:
117.15
UNSPSC Code:
12171500
NACRES:
NA.47
PubChem Substance ID:
EC Number:
203-770-8
Beilstein/REAXYS Number:
969510
MDL number:
InChI key
OWFXIOWLTKNBAP-UHFFFAOYSA-N
InChI
1S/C5H11NO2/c1-5(2)3-4-8-6-7/h5H,3-4H2,1-2H3
SMILES string
CC(C)CCON=O
assay
96%
form
liquid
technique(s)
titration: suitable
color
colorless to green-yellow, colorless to yellow
refractive index
n20/D 1.386 (lit.)
bp
99 °C (lit.)
mp
<-80 °C
solubility
water: soluble 0.38 g/L at 25 °C
density
0.872 g/mL at 25 °C (lit.)
application(s)
diagnostic assay manufacturing
hematology
histology
storage temp.
2-8°C
Quality Level
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General description
亚硝酸异戊酯（Isopentyl nitrite或isoamyl nitrite），别名亚硝戊酯，是一种氧化剂。可作为亚磷酰胺的亚硝化剂，亚磷酰胺在亚硝化时重排为磷酸三酯。
Application
亚硝酸异戊酯的用途如下：
- 作为多壁碳纳米管功能化的自由基引发剂。
- 作为制备4-羧基苯基重氮盐四氟硼酸盐的试剂。
- 合成过氧亚硝基 (ONOO-)。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-4.0 °F - closed cup
flash_point_c
-20 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Electron transfer at Au surfaces modified by Tethered Osmium bipyridine?pyridine complexes
Journal of Solid State Electrochemistry, 11:11, 1511-1520 null
New insights into the functionalization of multi-walled carbon
nanotubes with aniline derivatives
nanotubes with aniline derivatives
Lipinska M E
Carbon, 50, 3280 -33294 (2012)
Tetrahedron Letters, 31, 1113-1113 (1990)
Comparing nitrosative versus oxidative stress toward zinc finger-dependent transcription. Unique role for NO.
Kroncke KD
The Journal of Biological Chemistry, 277(15), 13294-13301 (2002)
Hossein Mehrabi
Ultrasonics sonochemistry, 15(4), 279-282 (2007-10-26)
The reaction of 6-acylmethylphenanthridines with isoamyl nitrite results alpha-oximino-6-acylmethylphenanthridines in 73-95% yields in DMF under ultrasound irradiation. Compared with conventional methods, the main advantages of the present procedure are milder conditions, shorter reaction time and higher yields.
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