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Merck
CN

14795

Sigma-Aldrich

N,N,N′,N′-四甲基-1,8-萘二胺

purum, ≥99.0% (NT)

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别名:
1,8-双二甲氨基萘, DMAN, Proton-sponge®
经验公式(希尔记法):
C14H18N2
CAS号:
分子量:
214.31
Beilstein:
396782
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

等级

purum

质量水平

检测方案

≥99.0% (NT)

形式

solid

mp

45-49 °C

SMILES字符串

CN(C)c1cccc2cccc(N(C)C)c12

InChI

1S/C14H18N2/c1-15(2)12-9-5-7-11-8-6-10-13(14(11)12)16(3)4/h5-10H,1-4H3

InChI key

GJFNRSDCSTVPCJ-UHFFFAOYSA-N

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应用

N,N,N′,N′-四甲基-1,8-萘二胺用于多电荷寡核苷酸阴离子的质子化。它用作硝酸铋催化苯甲醛与乙酸酐反应的试剂。在液-液萃取法发酵液中有机酸分离过程中用作萃取剂

其他说明

具有独特性质的胺类强碱("质子海绵")

法律信息

Proton-sponge is a registered trademark of Merck KGaA, Darmstadt, Germany

象形图

Exclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Bismuth compounds in organic synthesis. Bismuth nitrate catalyzed chemoselective synthesis of acylals from aromatic aldehydes.
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A single sonic spray source has been used to generate both positive and negative ions for subsequent ion/ion reaction experiments. Ion/ion reactions took place after ions of each polarity were sequentially injected into a linear ion trap, where axial trapping
Extractant screening for liquid-liquid extraction in environmentally benign production routes.
Krzyzaniak A, et al.
Chemical Engineering Transactions, 24, 709-714 (2011)

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