等级
purum
质量水平
检测方案
≥97.0%
形式
solid
反应适用性
core: thallium
reagent type: catalyst
SMILES字符串
CC(=O)O[Tl]
InChI
1S/C2H4O2.Tl/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
InChI key
HQOJMTATBXYHNR-UHFFFAOYSA-M
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一般描述
Thallium (I) acetate functions as a catalyst to enhance the rate of chemical reactions in the synthesis of isothiocyanates from isocyanides and disulfides. In addition, it is also used as the source of thallium ions in organic solvents for electrochemical reactions.
应用
- Thallium Use: An Overview: Offers a comprehensive overview of Thallium(I) acetate′s use in organic synthesis in the oxidation of olefins and hydrocarbons, and in epoxidation and polymerization reactions (Genchi et al., 2021).
警示用语:
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
法规信息
铊类化学品
危险化学品
The thallium (I) salt-catalyzed formation of isothiocyanates from isocyanides and disulfides
Bulletin of the Chemical Society of Japan, 50(10), 2785-2788 (1977)
The Journal of Organic Chemistry, 48, 2021-2021 (1983)
Electrochemical Behavior of Thallium Ion in Organic Solvents and its Application to Organic Synthesis
ECS Transactions, 13(20), 7-7 (2008)
Tetrahedron Letters, 33, 7789-7789 (1992)
Toxicology, 49(1), 121-129 (1988-04-01)
The toxic effect of thallium added to the bath solution was studied with intra- and extracellular recordings from mammalian nerve-muscle preparations. To elucidate the target region, 3 different functional parameters were studied: (1) Post-synaptic endplate potentials (EPPs) resulting from evoked
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