112682
甲酸乙酯
reagent grade, 97%
别名:
蚁酸乙酯
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线性分子式:
HCOOC2H5
化学文摘社编号:
分子量:
74.08
NACRES:
NA.21
PubChem Substance ID:
eCl@ss:
39022251
UNSPSC Code:
12352100
EC Number:
203-721-0
MDL number:
Beilstein/REAXYS Number:
906769
产品名称
甲酸乙酯, reagent grade, 97%
InChI key
WBJINCZRORDGAQ-UHFFFAOYSA-N
InChI
1S/C3H6O2/c1-2-5-3-4/h3H,2H2,1H3
SMILES string
CCOC=O
grade
reagent grade
vapor density
2.5 (vs air)
vapor pressure
15.16 psi ( 55 °C)
3.79 psi ( 20 °C)
assay
97%
autoignition temp.
851 °F
expl. lim.
16 %
refractive index
n20/D 1.359 (lit.)
bp
52-54 °C (lit.)
mp
−80 °C (lit.)
density
0.921 g/mL at 20 °C (lit.)
Quality Level
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Application
甲酸乙酯已用于 N -（2-三乙氧基硅丙基）甲酰胺的制备。已用于合成 N -甲基-3-苯基双环 [2.2.1] 庚烷-2-胺盐酸盐。
可用于异黄酮的合成。
可用于异黄酮的合成。
General description
甲酸乙酯是甲酸的乙酯。它的微波光谱表明存在两种异构体形式，它们的羰基氧原子上有乙基 顺式 ，但在-CH 2 -O 键上有不同的甲基排列。有研究报道了其热分解生成相应的的酸和烯烃的动力学。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
-4.0 °F - closed cup
flash_point_c
-20 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
Tristan F Kinde et al.
Analytical chemistry, 87(5), 2702-2709 (2015-02-11)
While the use of sodium dodecyl sulfate (SDS) in separation buffers allows efficient analysis of complex mixtures, its presence in the sample matrix is known to severely interfere with the mass-spectrometric characterization of analyte molecules. In this article, we report
Microwave spectrum and rotational isomerism of ethyl formate.
Riveros JM and Wilson Jr EB.
J. Chem. Phys. , 46(12), 4605-4612 (1967)
Eagleson M.
Concise Encyclopedia Chemistry, 413-413 (1994)
The kinetics of the pyrolysis of ethyl and isopropyl formates and acetates.
Blades AT.
Canadian Journal of Chemistry, 32(4), 366-372 (1954)
Hanjin Im et al.
Bioresource technology, 193, 386-392 (2015-07-06)
This work addresses an unprecedented way of co-producing biodiesel (FAEE) and valuable chemicals of ethyl levulinate (EL), ethyl formate (EF) and diethyl ether (DEE) from wet in situ transesterification of microalgae. EL, EF, and DEE were significantly produced up to
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