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Merck
CN

108170

Sigma-Aldrich

硝基甲烷

reagent grade, 96%

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经验公式(希尔记法):
CH3NO2
CAS号:
分子量:
61.04
Beilstein:
1698205
EC 号:
MDL编号:
UNSPSC代码:
12352102
PubChem化学物质编号:

等级

reagent grade

蒸汽密度

2.1 (vs air)

蒸汽压

2.7 mmHg

检测方案

96%

形式

liquid

自燃温度

784 °F

expl. lim.

7.3 %, 33 °F

折射率

n20/D 1.382 (lit.)

bp

101.2 °C (lit.)

mp

−29 °C (lit.)

密度

1.127 g/mL at 25 °C (lit.)

SMILES字符串

C[N+]([O-])=O

InChI

1S/CH3NO2/c1-2(3)4/h1H3

InChI key

LYGJENNIWJXYER-UHFFFAOYSA-N

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其他说明

A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.

警示用语:

Warning

危险分类

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2

WGK

WGK 2

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Metal ion encapsulation: cobalt cages derived from polyamines, formaldehyde, and nitromethane.
Geue RJ, et al.
Journal of the American Chemical Society, 106(19), 5478-5488 (1984)
The catalytic chemistry of nitromethane over Co-ZSM5 and other catalysts in connection with the methane-NOxSCR reaction.
Cowan AD, et al.
J. Catal., 176(2), 329-343 (1998)
Ryan R Walvoord et al.
Organic letters, 14(16), 4086-4089 (2012-07-31)
An efficient cross-coupling reaction of aryl halides and nitromethane was developed with the use of parallel microscale experimentation. The arylnitromethane products are precursors for numerous useful synthetic products. An efficient method for their direct conversion to the corresponding oximes and
Huachang Hong et al.
The Science of the total environment, 444, 196-204 (2012-12-29)
The formations of THMs, HAAs, and HNMs from chlorination and chloramination of water from Jinlan Reservoir were investigated in this study. Results showed that monochloramine rather than chlorine generally resulted in lower concentration of DBPs, and the DBPs formation varied
Naomi Rom et al.
The journal of physical chemistry. A, 115(36), 10181-10202 (2011-08-05)
The decomposition mechanism of hot liquid nitromethane at various compressions was studied using reactive force field (ReaxFF) molecular dynamics simulations. A competition between two different initial thermal decomposition schemes is observed, depending on compression. At low densities, unimolecular C-N bond

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