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Merck
CN
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文件

安全信息

07618

Sigma-Aldrich

反式-2-氨基环己烷羧酸

≥97.0%

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经验公式（希尔记法）:
C7H13NO2
CAS号:
5691-19-0
分子量:
143.18
Beilstein:
3196018
MDL编号:
MFCD00145418
UNSPSC代码:
12352106
PubChem化学物质编号:
329748496
NACRES:
NA.22

质量水平

100

检测方案

≥97.0%

形式

powder

反应适用性

reaction type: solution phase peptide synthesis

颜色

white to faint beige

mp

~255 °C (dec.)

应用

peptide synthesis

SMILES字符串

N[C@@H]1CCCC[C@H]1C(O)=O

InChI

1S/C7H13NO2/c8-6-4-2-1-3-5(6)7(9)10/h5-6H,1-4,8H2,(H,9,10)/t5-,6-/m1/s1

InChI key

USQHEVWOPJDAAX-PHDIDXHHSA-N

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WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

法规信息

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William C Pomerantz et al.
Journal of the American Chemical Society, 133(34), 13604-13613 (2011-08-06)
We have examined the effect of β-peptide modifications on the propensity of these helical molecules to form lyotropic liquid crystalline (LC) phases in water. All of the β-peptides we have examined contain 10 residues. In each case, at least three
Anasztázia Hetényi et al.
Journal of the American Chemical Society, 127(2), 547-553 (2005-01-13)
Homo-oligomers constructed by using trans-2-aminocyclohexanecarboxylic acid monomers without protecting groups were studied. Both ab initio theory and NMR measurements showed that the tetramer tends to adopt a 10-helix motif, while the pentamer and hexamer form the known 14-helix. It was
Betas are brought into the fold.
B L Iverson
Nature, 385(6612), 113-113 (1997-01-09)
Anna R M Hyyryläinen et al.
Journal of mass spectrometry : JMS, 45(2), 198-204 (2009-11-28)
Differentiation of beta-amino acid enantiomers with two chiral centres was investigated by kinetic method with trimeric metal-bound complexes. Four enantiomeric pairs of beta-amino acids were studied: cis-(1R,2S)-, cis-(1S,2R)-, trans-(1R,2R)- and trans-(1S,2S)-2-aminocyclopentanecarboxylic acids (cyclopentane beta-amino acids), and cis-(1R,2S)-, cis-(1S,2R)-, trans-(1R,2R)-, and
M Marastoni et al.
Arzneimittel-Forschung, 49(1), 6-12 (1999-02-24)
The solid phase synthesis, based on the Fmoc chemical protocol, was used to prepare ten deltorphin C (Del-C; H-Tyr-D-Ala-Phe-Asp-Val-Val-Gly-NH2) analogues containing cis- and trans- 2 or 3- or 4- aminocyclohexanecarboxylic acid (ACCA) residues at position 2. ACCA-peptides showed high resistance
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