跳转至内容
Merck
CN
所有图片(1)

文件

07033

Sigma-Aldrich

N,N-双-((S)-1-苯基乙基)二苯并[d,f][1,3,2]二氧杂膦-6-胺

≥99.0%

别名:

(S,S)-N-(5,7-二氧杂-6-磷杂二苯并[a,c]环庚烯-6-基)双(1-苯乙基)胺, O,O′-(2,2′-联苯二基)N,N-双[(S)-1-苯基乙基]亚磷酰胺, BIPOL-A1(S)

登录查看公司和协议定价
所有图片(1)

About This Item

经验公式（希尔记法）:
C28H26NO2P
CAS号:
376355-58-7
分子量:
439.49
MDL编号:
MFCD08277033
UNSPSC代码:
12352005
PubChem化学物质编号:
329748328
NACRES:
NA.22

质量水平

100

检测方案

≥99.0%

形式

powder

旋光性

[α]/D -250±10°, c = 1 in toluene

反应适用性

reaction type: click chemistry

mp

99-102 °C

SMILES字符串

C[C@H](N([C@@H](C)c1ccccc1)P2Oc3ccccc3-c4ccccc4O2)c5ccccc5

InChI

1S/C28H26NO2P/c1-21(23-13-5-3-6-14-23)29(22(2)24-15-7-4-8-16-24)32-30-27-19-11-9-17-25(27)26-18-10-12-20-28(26)31-32/h3-22H,1-2H3

InChI key

JISGHECLGYELKD-UHFFFAOYSA-N

应用

N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:
  • In the iridium catalyzed allylic arylation.
  • To prepare a copper complex (Cu2X2L3), which is used to detect the transmetalation intermediates in asymmetric addition reactions using ZnEt2.

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

Choose from one of the most recent versions:

分析证书(COA)

Lot/Batch Number
1206180V
1206180

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Elusive Transmetalation Intermediate in Copper-Catalyzed Conjugate Additions: Direct NMR Detection of an Ethyl Group Attached to a Binuclear Phosphoramidite Copper Complex
von Rekowski F, et al.
Journal of the American Chemical Society, 136(32), 11389-11395 (2014)
Enantioselective Iridium-Catalyzed Allylic Arylation
Polet D, et al.
Chemistry?A European Journal , 15(5), 1205-1216 (2009)

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门