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Merck
CN

06849

1-甲基咪唑 溶液

filtered through a 1μm filter

别名:

1-Methylimidazole solution

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关于此项目

经验公式(希尔记法):
C4H6N2
化学文摘社编号:
分子量:
82.10
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
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InChI

1S/C4H6N2/c1-6-3-2-5-4-6/h2-4H,1H3

SMILES string

Cn1ccnc1

InChI key

MCTWTZJPVLRJOU-UHFFFAOYSA-N

quality

filtered through a 1μm filter

impurities

<0.01% water

Application

1-Methylimidazole has been used in a study to elaborate on the use of differential scanning calorimetry as a new indirect method for determination of vaporization enthalpies. 1-Methylimidazole has also been used in a study that analyzed the base content in in-service oils by Fourier Transform Infrared Spectroscopy.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

1.4 °F

flash_point_c

-17 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

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Sergey P Verevkin et al.
The journal of physical chemistry. B, 116(14), 4276-4285 (2012-03-23)
Differential scanning calorimetry (DSC) has been used to measure enthalpies of synthesis reactions of the 1-alkyl-3-methylimidazolium bromide [C(n)mim][Br] ionic liquids from 1-methylimidazole and n-alkyl bromides (with n = 4, 5, 6, 7, and 8). The optimal experimental conditions have been
Sadia Ehsan et al.
Journal of laboratory automation, 17(3), 201-210 (2012-02-24)
An automated FTIR method for the determination of the base content (BC(pKa)) of oils at rates of > 120 samples/h has been developed. The method uses a 5% solution of trifluoroacetic acid in 1-propanol (TFA/P) added to heptane-diluted oil to
Malachy McCann et al.
Dalton transactions (Cambridge, England : 2003), 41(21), 6516-6527 (2012-04-06)
[Ag(2)(9-aca)(2)] (1) (9-acaH = 9-anthracenecarboxylic acid) reacts with a series of imidazoles to give [Ag(imidH)(2.3)(CH(3)CN)(0.7)](9-aca) (3), [Ag(6)(imidH)(4)(9-aca)(6)(MeOH)(2)] (4), {[Ag(1-Me-imid)(2)](2)[Ag(4)(9-aca)(6)]} (5), {[Ag(1-Bu-imid)(2)](2)[Ag(4)(9-aca)(6)]} (6) and [Ag(apim)](9-aca)·H(2)O (7) (imidH = imidazole; 1-Me-imid = 1-methylimidazole; 1-Bu-imid = 1-butylimidazole; apim = 1-(3-aminopropyl)imidazole). The mononuclear complex
Zhan-Yong Wang et al.
The Journal of organic chemistry, 77(15), 6608-6614 (2012-07-19)
A well-defined NHC-Pd(II)-Im complex 1 was found to be an effective catalyst for the Suzuki-Miyaura coupling of aryl sulfonates including tosylates and phenylsulfonates with arylboronic acids, giving the desired coupling products in good to high yields. Acceptable yields can also
Bhaskar Sharma et al.
The journal of physical chemistry. A, 115(10), 1971-1984 (2011-02-22)
Quantum chemical [MP2(FULL)/6-311++G-(d,p)] calculations are done on the binding of hydrated Li(+), Na(+), K(+), Mg(2+), Cu(+), and Zn(2+) metal ions with biologically relevant heteroaromatics such as imidazole and methylimidazole. The computed interaction energies are found to be in good agreement

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