推荐产品
等级
purum
质量水平
检测方案
≥98.0% (GC)
形式
liquid
折射率
n20/D 1.548 (lit.)
n20/D 1.548
bp
110-113 °C/0.5 mmHg (lit.)
密度
1.189 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
C=CCS(=O)(=O)c1ccccc1
InChI
1S/C9H10O2S/c1-2-8-12(10,11)9-6-4-3-5-7-9/h2-7H,1,8H2
InChI key
KYPIULIVYSQNNT-UHFFFAOYSA-N
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应用
Possible usages of allyl phenyl sulfone:
- It can undergo isomerization by the nonionic proazaphosphatrane catalysts under mild reaction conditions.
- It can react with epoxymesylate to give cycloalkane derivative. This method has been employed in the synthesis of marine eicosanoid bacillariolides I-III.
- It can undergo electrocatalytic additions to vinyl sulfones catalyzed by an electrogenerated base.
Starting material for the preparation of 1-alkyl-2-methylethenes; Michael additions to enones; Synthesis of α,β-unsaturated nitriles
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
235.4 °F
闪点(°C)
113 °C
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Journal of the Chemical Society. Perkin Transactions 1, 123-123 (1977)
Proazaphosphatrane P (RNCH2CH2) 3N (R= Me, i?Pr)?Catalyzed Isomerization of Allylaromatics, Allyl Phenyl Sulfide, Allyl Phenyl Sulfone, and bis?Allylmethylene Double Bond?Containing Compounds
Advanced Synthesis & Catalysis, 348(1?2), 111-117 (2006)
Tetrahedron Letters, 22, 1905-1905 (1981)
The Journal of Organic Chemistry, 46, 4817-4817 (1981)
Highly efficient, catalytic bis addition reactions of allyl phenyl sulfone to vinyl sulfones.
Tetrahedron Letters, 45(25), 4841-4845 (2004)
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