06044
3-(烯丙氧羰基氨基)-1-丙醇
≥97.0% (GC)
别名:
N-(3-羟基丙基)氨基甲酸烯丙酯
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关于此项目
线性分子式:
CH2=CHCH2OCONH(CH2)3OH
化学文摘社编号:
分子量:
159.18
UNSPSC Code:
12352202
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
7579395
Assay:
≥97.0% (GC)
InChI
1S/C7H13NO3/c1-2-6-11-7(10)8-4-3-5-9/h2,9H,1,3-6H2,(H,8,10)
SMILES string
OCCCNC(=O)OCC=C
InChI key
ZKLMTPLBEYYNKM-UHFFFAOYSA-N
assay
≥97.0% (GC)
reaction suitability
reagent type: cross-linking reagent
refractive index
n20/D 1.472
density
1.097 g/mL at 20 °C (lit.)
Quality Level
Other Notes
在柔红酮衍生物中引入氨丙基连接基。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
228.2 °F - closed cup
flash_point_c
109 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Zoltán Dienes et al.
The Journal of organic chemistry, 61(20), 6958-6970 (1996-10-04)
The BF(3).Et(2)O-promoted Diels-Alder addition of 1-acetylvinyl RADO(Et)-ate (RADO(Et)-ate = 3-ethyl-2-oxo-6,8-dioxa-3-azabicyclo[3.2.1]octane-7-exo-carboxylate) to 1-(dimethoxymethyl)-2,3,5,6-tetramethylidene-7-oxabicyclo[2.2.1]heptane led to one major monoadduct that added to 1,2-didehydrobenzene and was converted into (-)-4-demethoxy-7-deoxydaunomycinone and (2R)-12-acetoxy-2-acetyl-5-(bromomethyl)-1,2,3,4-tetrahydronaphthacen-2-yl RADO(Et)-ate. The latter compound was used to construct (8R)-8-acetyl-6,8-dihydroxy-11-[[(3'-[(aminopropyl)oxy]-, -4'-[(aminobutyl)oxy], and -5'-[(aminopentyl)oxy]methyl]-7,8,9,10-tetrahydronaphthacene-5,12-dione
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