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Merck
CN

04004

Sigma-Aldrich

红磷

≥97.0%

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别名:
P
经验公式(希尔记法):
P
CAS号:
分子量:
30.97
EC 号:
MDL编号:
UNSPSC代码:
12141909
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

0.02 (vs air)

质量水平

蒸汽压

0.03 mmHg ( 21 °C)
1 mmHg ( 76.6 °C)

检测方案

≥97.0%

自燃温度

500 °F

反应适用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

电阻率

10 μΩ-cm, 20°C

mp

416 °C (subl.) (lit.)

密度

2.34 g/mL at 25 °C (lit.)

痕量阳离子

Fe: ≤2000 mg/kg

储存温度

2-8°C

SMILES字符串

[P]

InChI

1S/P

InChI key

OAICVXFJPJFONN-UHFFFAOYSA-N

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一般描述

Red phosphorus is the most common allotrope ofphosphorus due to its relative stability compared to white phosphorus. It has a variety of uses including, but notlimited to, use as a catalyst, battery anode, flame retardant, and igniter.

应用

Red phosphorus can be used as a:
  • Photocatalyst for the formation of H2 from water.
  • Catalyst in the synthesis of tris(2-pyridyl)phosphine by reacting with 2-bromopyridine in the presence of a base.
  • Flame retardant along with aluminum oxide in recycled poly(ethylene terephthalate).
  • Anode material in combination with carbon composites for sodium-ion batteries.

象形图

Flame

警示用语:

Warning

危险声明

危险分类

Aquatic Chronic 3 - Flam. Sol. 2

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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Expedient one-pot organometallics-free synthesis of tris (2-pyridyl) phosphine from 2-bromopyridine and elemental phosphorus
Trofimov BA, et al.
Tetrahedron Letters, 53(19), 2424-2427 (2012)
New Evidence Concerning the Structure of Amorphous Red Phosphorus
Hartl H
Angewandte Chemie (International Edition in English), 34(23-24), 2637-2638 (1996)
An amorphous red phosphorus/carbon composite as a promising anode material for sodium ion batteries
Kim Y, et al.
Advanced Materials, 25(22), 3045-3049 (2013)
Red phosphorus: an elemental photocatalyst for hydrogen formation from water
Wang F, et al.
Applied Catalysis. B, Environmental, 111, 409-414 (2012)
Phospham-A stable phosphorus-rich flame retardant
Weil EDD and Patel NG
Fire and Materials, 18(1), 1-7 (1994)

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