蒸汽压
10 mmHg ( 656 °C)
质量水平
等级
purum
检测方案
≥99.5%
反应适用性
core: copper
reagent type: catalyst
mp
605 °C (lit.)
密度
5.62 g/mL at 25 °C (lit.)
痕量阴离子
sulfate (SO42-): ≤5000 mg/kg
痕量阳离子
Fe: ≤50 mg/kg
SMILES字符串
[Cu+].[I-]
InChI
1S/Cu.HI/h;1H/q+1;/p-1
InChI key
LSXDOTMGLUJQCM-UHFFFAOYSA-M
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应用
碘化铜(I)可与氟化铯联用促进 Stille 偶联反应。它还可以在六甲基磷酰三胺中介导烯硫醇盐离子与不同的
非活化芳基碘化物反应，形成芳基硫化物。
碘化铜(I)可用于催化：
非活化芳基碘化物反应，形成芳基硫化物。
碘化铜(I)可用于催化：
- 芳基卤的硫醚化。此过程使用湿聚乙二醇中的硫脲和烷基溴化物，以碳酸钾作为碱。
- 乙炔与金属卤化物在二乙胺中反应形成过渡金属炔基络合物。
- 末端炔烃与苯基硫属基卤化物反应形成炔基硒化物、硫化物和碲化物。
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT RE 1 Oral
靶器官
Thyroid
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Facile substitution reaction between nonactivated aryl iodides and arenethiolates in the presence of copper (I) iodide.
Suzuki H, et al.
Chemistry Letters (Jpn), 9(11), 1363-1364 (1980)
Significant enhancement of the Stille reaction with a new combination of reagents?copper (I) iodide with cesium fluoride.
Mee SP, et al.
Chemistry?A European Journal , 11(11), 3294-3308 (2005)
One?Pot Thioetherification of Aryl Halides Using Thiourea and Alkyl Bromides Catalyzed by Copper (I) Iodide Free from Foul?Smelling Thiols in Wet Polyethylene Glycol (PEG 200).
Firouzabadi H, et al.
Advanced Synthesis & Catalysis, 352(1), 119-124 (2010)
Roberta Berrino et al.
The Journal of organic chemistry, 77(5), 2537-2542 (2012-01-31)
Free NH 3,3-diarylacrylamides are cyclized to substituted 2-quinolones in the presence of CuI, PPh(3), and KO-t-Bu in o-xylene at 100 °C. The reaction proceeds through a C-H functionalization/C-N bond formation process. With unsymmetrical 3,3-diarylacrylamides, high selectivity is observed using substrates
Min Jiang et al.
Organic letters, 14(6), 1420-1423 (2012-03-08)
A domino synthesis of 5,12-dihydroindolo[2,1-b]quinazoline derivatives via copper-catalyzed Ullmann-type intermolecular C-C and intramolecular C-N couplings is reported. Good yields of various 5,12-dihydroindolo[2,1-b]quinazoline derivatives were obtained. Reaction scopes, limitations, and the reaction mechanism are discussed.
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