03140
碘化亚铜
≥99.5%, purum
别名:
碘化亚铜
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关于此项目
经验公式（希尔记法）:
CuI
化学文摘社编号:
分子量:
190.45
UNSPSC Code:
12161600
eCl@ss:
38150105
PubChem Substance ID:
NACRES:
NA.22
EC Number:
231-674-6
MDL number:
产品名称
碘化亚铜, purum, ≥99.5%
SMILES string
[Cu+].[I-]
InChI
1S/Cu.HI/h;1H/q+1;/p-1
InChI key
LSXDOTMGLUJQCM-UHFFFAOYSA-M
vapor pressure
10 mmHg ( 656 °C)
grade
purum
assay
≥99.5%
reaction suitability
core: copper
reagent type: catalyst
core: copper
reaction type: click chemistry
mp
605 °C (lit.)
density
5.62 g/mL at 25 °C (lit.)
anion traces
sulfate (SO42-): ≤5000 mg/kg
cation traces
Fe: ≤50 mg/kg
Quality Level
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Application
碘化铜(I)可与氟化铯联用促进 Stille 偶联反应。它还可以在六甲基磷酰三胺中介导烯硫醇盐离子与不同的
非活化芳基碘化物反应，形成芳基硫化物。
碘化铜(I)可用于催化：
非活化芳基碘化物反应，形成芳基硫化物。
碘化铜(I)可用于催化：
- 芳基卤的硫醚化。此过程使用湿聚乙二醇中的硫脲和烷基溴化物，以碳酸钾作为碱。
- 乙炔与金属卤化物在二乙胺中反应形成过渡金属炔基络合物。
- 末端炔烃与苯基硫属基卤化物反应形成炔基硒化物、硫化物和碲化物。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT RE 1 Oral
target_organs
Thyroid
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Facile substitution reaction between nonactivated aryl iodides and arenethiolates in the presence of copper (I) iodide.
Suzuki H, et al.
Chemistry Letters (Jpn), 9(11), 1363-1364 (1980)
One?Pot Thioetherification of Aryl Halides Using Thiourea and Alkyl Bromides Catalyzed by Copper (I) Iodide Free from Foul?Smelling Thiols in Wet Polyethylene Glycol (PEG 200).
Firouzabadi H, et al.
Advanced Synthesis & Catalysis, 352(1), 119-124 (2010)
Significant enhancement of the Stille reaction with a new combination of reagents?copper (I) iodide with cesium fluoride.
Mee SP, et al.
Chemistry?A European Journal , 11(11), 3294-3308 (2005)
Convenient preparation of alkynyl selenides, sulfides and tellurides from terminal alkynes and prenylchalcogenyl halides in the presence of copper (I) iodide.
Braga AL, et al.
Tetrahedron Letters, 34(50), 8041-8042 (1993)
Chunfeng Meng et al.
Chemistry, an Asian journal, 14(23), 4289-4295 (2019-10-16)
Recently, carboxylate metal-organic framework (MOF) materials were reported to perform well as anode materials for lithium-ion batteries (LIBs); however, the presumed lithium storage mechanism of MOFs is controversial. To gain insight into the mechanism of MOFs as anode materials for
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