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等级
analytical standard
质量水平
蒸汽密度
2.1 (vs air)
方案
≥99.0% (GC)
自燃温度
784 °F
保质期
limited shelf life, expiry date on the label
expl. lim.
7.3 %, 33 °F
技术
HPLC: suitable
gas chromatography (GC): suitable
折射率
n20/D 1.382 (lit.)
n20/D 1.382
沸点
101.2 °C (lit.)
mp
−29 °C (lit.)
密度
1.127 g/mL at 25 °C (lit.)
应用
environmental
包装形式
neat
SMILES字符串
C[N+]([O-])=O
InChI
1S/CH3NO2/c1-2(3)4/h1H3
InChI key
LYGJENNIWJXYER-UHFFFAOYSA-N
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一般描述
Nitromethane belongs to the class of residual solvents which are volatile organic compounds (VOCs) that are employed in manufacturing processes of pharmaceutical industries.
应用
Nitromethane has been used as a reference standard for the determination of nitromethane in cigarette smoke by high-throughput solid phase microextraction coupled with gas chromatography−mass spectrometry (SPME-GC−MS) and in drug substances by static headspace GC. It may be used as a reference standard for the determination of nitromethane in gaseous and liquid samples by thermal desorption−GC-MS.
警示用语：
Warning
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2
储存分类代码
4.1A - Other explosive hazardous materials
WGK
WGK 2
闪点(°F)
95.0 °F - closed cup
闪点(°C)
35 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
易制爆化学品
危险化学品
Simultaneous analysis of 22 volatile organic compounds in cigarette smoke using gas sampling bags for high-throughput solid-phase microextraction.
Sampson, et al.
Analytical Chemistry, 86(14), 7088-7095 (2014)
Establishment of a knowledge base for identification of residual solvents in pharmaceuticals..
Liu, et al.
Analytica Chimica Acta, 575(2), 246-254 (2006)
Quality control in quantification of volatile organic compounds analysed by thermal desorption-gas chromatography-mass spectrometry.
Demeestere, et al.
Journal of Chromatography A, 1186(1-2), 348-357 (2008)
Ryan R Walvoord et al.
Organic letters, 14(16), 4086-4089 (2012-07-31)
An efficient cross-coupling reaction of aryl halides and nitromethane was developed with the use of parallel microscale experimentation. The arylnitromethane products are precursors for numerous useful synthetic products. An efficient method for their direct conversion to the corresponding oximes and
Junhong Shan et al.
Chemosphere, 86(4), 323-328 (2011-11-01)
In this study, the effects of pH, bromide and nitrite on the formation of halonitromethanes (HNMs) and trihalomethanes (THMs) from eight amino acids (glycine, alanine, serine, cysteine, aspartic acid, glutamic acid, lysine and histidine) and four amino sugars (glucosamine, galactosamine
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