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Merck
CN

02469

2-丁酮

analytical standard

别名:

MEK, 乙基甲基酮, 甲基乙基酮

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关于此项目

线性分子式:
C2H5COCH3
化学文摘社编号:
78-93-3
分子量:
72.11
NACRES:
NA.24
PubChem Substance ID:
329747439
EC Number:
201-159-0
Beilstein/REAXYS Number:
741880
MDL number:
MFCD00011648
UNSPSC Code:
12141716

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产品名称

2-丁酮, analytical standard

InChI key

ZWEHNKRNPOVVGH-UHFFFAOYSA-N

InChI

1S/C4H8O/c1-3-4(2)5/h3H2,1-2H3

SMILES string

CC(CC)=O

grade

analytical standard

vapor density

2.49 (vs air)

vapor pressure

71 mmHg ( 20 °C)

assay

≥99.9% (GC)

autoignition temp.

960 °F

shelf life

limited shelf life, expiry date on the label

expl. lim.

10.1 %

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.379 (lit.)
n20/D 1.379

bp

80 °C (lit.)

mp

−87 °C (lit.)

density

0.805 g/mL at 25 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
flavors and fragrances
food and beverages
personal care

format

neat

Quality Level

100

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相关类别

Application

2-Butanone may have been used as reference standard in solid-phase microextraction gas-chromatography (SPME-GC) for quantification of volatile compounds from dry-cured hams.

General description

2-Butanone also known as methyl ethyl ketone is a colorless fairly volatile liquid with a pleasant pungent odor. It is primarily used as a solvent, for making other chemicals, and for production of wax from petroleum. It is derived from refluxing methyl acetoacetate and dilute sulphuric acid. It finds application in manufacturing plastic, textile, paints, pharmaceuticals and cosmetics.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

supp_hazards

EUH066

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

30.2 °F - closed cup

flash_point_c

-1 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
易制毒化学品（3类）
此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCW4794
MKCS4455
MKCP3742
MKCL1082
MKCF4409

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Characterization of French and Spanish dry-cured hams: influence of the volatiles from the muscles and the subcutaneous fat quantified by SPME-GC.
Sanchez-Pe?a CM
Meat Science, 69(4), 635-645 (2005)
Cooper's Toxic Exposures Desk Reference with CD-ROM, 377-377 (1996)
S G Carmella et al.
Cancer research, 53(4), 721-724 (1993-02-15)
Metabolites of the tobacco-specific nitrosamine, 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone, a potent pulmonary carcinogen, have been quantified in the urine of 11 smokers. They were not detected in nonsmokers' urine. The metabolites, 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanol and its glucuronide, were detected in quantities of 0.23-1.0 and 0.57-6.5
L B Goldsmith et al.
Contact dermatitis, 19(5), 348-350 (1988-11-01)
Irritant contact dermatitis along with an increased transepidermal water loss can result from exposing the skin to solvents. A study of the interaction of various solvents with human stratum corneum was made using thin-layer chromatography. Comparison of 10 solvents (trichloroethylene
Chao Long et al.
Journal of hazardous materials, 203-204, 251-256 (2011-12-30)
A novel hypercrosslinked polymeric adsorbent (HY-1) with high surface area and specific bimodal pore size distribution in the regions of micropore (0.5-2.0 nm) and meso-macropore (30-70 nm) was prepared. Adsorption properties of benzene and methyl ethyl ketone (MEK) vapors onto
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