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Merck
CN

00768

Sigma-Aldrich

1-乙基-3-甲基咪唑四氟硼酸盐

for electrochemistry, ≥99.0% (HPLC)

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别名:
EMIMBF4
经验公式(希尔记法):
C6H11BF4N2
分子量:
197.97
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

等级

for electrochemistry

质量水平

检测方案

≥99.0% (HPLC)

形式

liquid

杂质

≤200 ppm water

折射率

n20/D 1.413 (lit.)

bp

>350 °C (lit.)

mp

15 °C (lit.)

密度

1.294 g/mL at 25 °C (lit.)

痕量阴离子

bromide (Br-): ≤10 mg/kg
chloride (Cl-): ≤10 mg/kg
nitrate (NO3-): ≤10 mg/kg
sulfate (SO42-): ≤10 mg/kg

SMILES字符串

F[B-](F)(F)F.CCn1cc[n+](C)c1

InChI

1S/C6H11N2.BF4/c1-3-8-5-4-7(2)6-8;2-1(3,4)5/h4-6H,3H2,1-2H3;/q+1;-1

InChI key

CUNYTRQQXKCRTJ-UHFFFAOYSA-N

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应用

1-乙基-3-甲基咪唑鎓四氟硼酸盐是室温离子液体,作为电解质,在电化学研究中广泛应用。目前已运用 NMR 技术对其扩散系数、 13C自旋晶格弛豫时间和核奥弗豪泽(Overhauser)增强效应进行分析,研究其氢键。同时在宽温范围内,对密度、粘度、热稳定性、表面张力、折射率和pH值等一些基本物理性质和化学性质进行了研究。

象形图

Exclamation markEnvironment

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 2

WGK

WGK 3

闪点(°F)

235.4 °F

闪点(°C)

113 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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NMR evidence of hydrogen bonding in 1-ethyl-3-methylimidazolium-tetrafluoroborate room temperature ionic liquid
Huang JF, et al.
Inorgorganica Chimica Acta, 320(1-2), 7-11 (2001)
Physical and electrochemical properties of 1-alkyl-3-methylimidazolium tetrafluoroborate for electrolyte
Nishida T, et al.
Journal of Fluorine Chemistry, 120(2), 135-141 (2003)
Electrochemical study of copper in a basic 1-ethyl-3-methylimidazolium tetrafluoroborate room temperature molten salt
Chen PY and Sun IW
Electrochimica Acta, 45(3), 441-450 (1999)
The Room Temperature Ionic Liquid 1-Ethyl-3-methylimidazolium Tetrafluoroborate: Electrochemical Couples and Physical Properties.
Fuller J, et al.
Journal of the Electrochemical Society, 144(11), 3881-3886 (1997)
Sungwon Lee et al.
Nature communications, 5, 5898-5898 (2014-12-20)
To measure electrophysiological signals from the human body, it is essential to establish stable, gentle and nonallergic contacts between the targeted biological tissue and the electrical probes. However, it is difficult to form a stable interface between the two for

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