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Merck
CN

00676

三辛基氧化膦

greener alternative

≥98.5% (GC), for extraction analysis

别名:

TOPO®, (Oct)3PO

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关于此项目

线性分子式:
[CH3(CH2)7]3PO
化学文摘社编号:
分子量:
386.63
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
EC Number:
201-121-3
MDL number:
Beilstein/REAXYS Number:
1796648
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产品名称

三辛基氧化膦, for extraction analysis, ≥98.5%

Quality Level

assay

≥98.5% (GC), ≥98.5%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

≤0.2% free acid (as H3PO4), ≤0.5% water

bp

201-202 °C/2 mmHg (lit.)

mp

50-52 °C (lit.), 52-55 °C

cation traces

Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤10 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Na: ≤10 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg

functional group

phosphine oxide

greener alternative category

SMILES string

CCCCCCCCP(=O)(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51OP/c1-4-7-10-13-16-19-22-26(25,23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

InChI key

ZMBHCYHQLYEYDV-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Application

Catalyst in:
  • Preparation of tetradentate planar-chiral hydroxy-substituted ferrocenecarboxaldimine Schiff base ligands
  • Reactions of allyl esters with hydrosilanes
  • Asymmetric cyanosilylation of aldehydes
  • Preparation of chlorothiol formates from thiols and phosgene

Legal Information

TOPO is a registered trademark of Life Technologies


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pictograms

Corrosion

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

446.0 °F - closed cup

flash_point_c

230 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Zeng, Z.; et al.
European Journal of Organic Chemistry, 1615-1615 (2008)
Niemeyer, J.; et al.
European Journal of Inorganic Chemistry, 680-680 (2010)
Wettling, T.; et al.
Ger. Offen., 1993-1993 null



全球贸易项目编号

货号GTIN
161713-10G04061838746580
161713-50G04061831828627
00676-10G04061838604637