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危险分类
Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码
8A - Combustible corrosive hazardous materials
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WGK 1
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Not applicable
闪点(°C)
Not applicable
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dust mask type N95 (US), Eyeshields, Faceshields, Gloves
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新产品
Chemical communications (Cambridge, England), 48(71), 8889-8891 (2012-07-21)
Unnatural α-amino acids containing dithiocarbamate side chains were synthesized by a one-pot reaction of in situ generated dithiocarbamate anions with sulfamidates. A wide range of these anions participated in the highly regio- and stereo-selective ring opening of sulfamidates to produce
The Journal of organic chemistry, 77(14), 5956-5964 (2012-06-21)
The efficiency of arylboron-based nucleophiles, boronic acid, potassium trifluoroborate, neopentylglycolboronate, and pinacol boronate in nickel-catalyzed Suzuki-Miyaura cross-coupling reactions with the two C-O electrophiles, mesylates, and sulfamates was compared. Arylboronic acid is the most reactive and most atom-economic of the four
The Journal of organic chemistry, 77(4), 1922-1930 (2012-01-31)
An intramolecular diamination of acrylates is reported using sulfamates as nitrogen sources. This reaction proceeds under palladium(II) catalysis with copper bromide as oxidant and gives rise to anti-configured 2,3-diamino carboxylates as bicyclic sulfamate derivatives. An aminobrominated intermediate within the diamination
Bioorganic & medicinal chemistry, 21(6), 1419-1426 (2012-12-04)
Targeting tumour associated carbonic anhydrase (CA, EC 4.2.1.1) isoforms IX and XII is now considered as a pertinent approach for the development of new cancer therapeutics against hypoxic tumours. In the last period, with the help of X-ray crystallography, much
Angewandte Chemie (International ed. in English), 51(14), 3354-3357 (2012-02-22)
Enhanced receptor selectivity: carbonic anhydrase inhibitors are relevant for both cancer diagnosis and therapy. Combining non-radioactive Re compounds with their radioactive (99m)Tc homologs enables the use of identical molecules for therapy and imaging (theragnostic). The syntheses and in vitro evaluation
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