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Merck
CN

28-1310

硝酸银

JIS special grade, ≥99.8%

别名:

硝酸银(I)盐

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线性分子式:
AgNO3
化学文摘社编号:
分子量:
169.87
UNSPSC Code:
12352302
PubChem Substance ID:
MDL number:
Assay:
≥99.8%
Grade:
JIS special grade
Form:
solid
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InChI

1S/Ag.NO3/c;2-1(3)4/q+1;-1

SMILES string

[O-][N+]([O-])=O.[Ag+]

InChI key

SQGYOTSLMSWVJD-UHFFFAOYSA-N

grade

JIS special grade

vapor density

5.8 (vs air)

assay

≥99.8%

form

solid

availability

available only in Japan

mp

212 °C (dec.) (lit.)

storage temp.

15-25°C

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General description

Silver nitrate is a versatile reagent that can be prepared by reacting silver with nitric acid. It is used in various fields such as organic synthesis, photography, silver paints, dyes, chemical analysis, gravimetric analysis, and pharmaceutical preparations.

Application

Silver nitrate can be used as a catalyst in the:
  • [3+2]-Cycloaddition of Ͱ-diazocarbonyl compounds with arenediazonium salts to synthesize 2,5-disubstituted tetrazoles.
  • Oxidation of aromatic, aliphatic, and conjugated aldehydes to corresponding carboxylic acids in the presence of H2O2 as an oxidant.
  • Lactamization of methyl Ͱ,Ͱ-disubstituted Ͱ-isocyanoacetates with primary amines to synthesize 3,5,5-trisubstituted imidazolones.

It can also be used as a:
  • Reagent to synthesize bisazetanes from the oxidation of azetidine.

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Repr. 1B - Skin Corr. 1A

存储类别

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number

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Irina Blinova et al.
Environmental science and pollution research international, 20(5), 3456-3463 (2012-11-13)
Although silver nanoparticles (NPs) are increasingly used in various consumer products and produced in industrial scale, information on harmful effects of nanosilver to environmentally relevant organisms is still scarce. This paper studies the adverse effects of silver NPs to two
Tao Xu et al.
Organic letters, 14(21), 5416-5419 (2012-10-24)
A silver-catalyzed intramolecular oxidative aminofluorination of alkynes has been developed by using NFSI as a fluorinating reagent. This reaction represents an efficient method for the synthesis of various 4-fluoroisoquinolines and 4-fluoropyrrolo[α]isoquinolines.
Patrycja Bober et al.
Biomacromolecules, 15(10), 3655-3663 (2014-08-28)
In this work, flexible and free-standing composite films of nanofibrillated cellulose/polypyrrole (NFC/PPy) and NFC/PPy-silver nanoparticles (NFC/PPy-Ag) have been synthesized for the first time via in situ one-step chemical polymerization and applied in potential biomedical applications. Incorporation of NFC into PPy
Gownolla Malegowd Raghavendra et al.
Carbohydrate polymers, 93(2), 553-560 (2013-03-19)
Natural carbohydrates (polysaccharides): gum acacia (GA) and gaur gum (GG) were employed in dilute solutions: 0.3%, 0.5% and 0.7% (w/v), as effective reductants for the green synthesis of silver nanoparticles (AgNPs) from AgNO3. The formed AgNPs were impregnated into cellulose
Ali Hebeish et al.
Carbohydrate polymers, 92(1), 407-413 (2012-12-12)
Innovative CMC-based hydrogels with great potentials for usage in medical area were principally synthesized as per two strategies .The first involved reaction of epichlorohydrin in alkaline medium containing silver nitrate to yield silver nano-particles (AgNPs)-loaded CMC hydrogel. While CMC acted

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