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Merck
CN

24-2710

Sigma-Aldrich

三氯氧磷(V)

SAJ first grade, ≥98.0%

别名:

三氯氧化磷(V), 磷酰三氯

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About This Item

线性分子式:
POCl3
CAS号:
分子量:
153.33
EC 号:
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:

等级

SAJ first grade

蒸汽密度

5.3 (vs air)

蒸汽压

104 mmHg ( 50 °C)
28 mmHg ( 20 °C)

方案

≥98.0%

表单

liquid

存货情况

available only in Japan

pH值(酸碱度)

1 (20 °C)

沸点

105.8 °C (lit.)

mp

1.25 °C (lit.)

密度

1.645 g/mL at 25 °C (lit.)

SMILES字符串

ClP(Cl)(Cl)=O

InChI

1S/Cl3OP/c1-5(2,3)4

InChI key

XHXFXVLFKHQFAL-UHFFFAOYSA-N

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Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1 Inhalation

靶器官

Respiratory Tract

补充剂危害

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Changjiang Yu et al.
Angewandte Chemie (International ed. in English), 51(31), 7688-7691 (2012-06-26)
Three for one: Pyrrolyldipyrromethenes having different functional groups were efficiently synthesized from POCl(3)-promoted condensations between 5-chloro-2-formylpyrrole or isoindole derivatives and suitable pyrrole or indole fragments through a novel nucleophilic aromatic substitution of the initially formed protonated azafulvene rings.
D M Badgujar et al.
Journal of hazardous materials, 172(1), 276-279 (2009-08-12)
1,2-Bis(2,4,6-trinitrophenyl) hydrazine (3) is one of the precursors in the synthesis of an important energetic material viz., hexanitrazobenzene. The simple and convenient lab scale synthesis of title compound (3) was carried out by the condensation of picryl chloride (2) with
Simple coupling reaction between amino acids and weakly nucleophilic heteroaromatic amines.
Gilles Quéléver et al.
Journal of combinatorial chemistry, 6(5), 695-698 (2004-09-14)
Xiaohu Deng et al.
The Journal of organic chemistry, 76(20), 8262-8269 (2011-09-09)
A POCl(3)-mediated, direct amination reaction of heterocyclic amides/ureas with NH-heterocycles or N-substituted anilines is described. Compared to the existing methods, this operationally simple protocol provides unique reactivity and functional group compatibility because of the metal-free, acidic reaction conditions. The yields
Bo Qin et al.
Chemistry, an Asian journal, 6(12), 3298-3305 (2011-07-23)
POCl(3)-mediated one-pot macrocyclization allows the highly selective formation of five-residue macrocycles that are rigidified by internally placed intramolecular hydrogen bonds. Mechanistic investigation by using tailored competition experiments and kinetic simulation provides a comprehensive model, supporting a chain-growth mechanism underlying the

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