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Merck
CN

18-1605

高氯酸锂

SAJ special grade, ≥99.0%

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线性分子式:
LiClO4
化学文摘社编号:
分子量:
106.39
UNSPSC Code:
12352302
PubChem Substance ID:
EC Number:
232-237-2
MDL number:
Assay:
≥99.0%
Grade:
SAJ special grade
Form:
crystalline
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InChI key

MHCFAGZWMAWTNR-UHFFFAOYSA-M

InChI

1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

SMILES string

[Li+].[O-]Cl(=O)(=O)=O

grade

SAJ special grade

assay

≥99.0%

form

crystalline

reaction suitability

reagent type: oxidant

availability

available only in Japan

pH

6.0-9.5 (25 °C, 106.4 g/L)

mp

236 °C (lit.)

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signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

存储类别

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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分析证书(COA)

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Witold Darlewski et al.
Journal of hazardous materials, 175(1-3), 460-467 (2009-11-17)
A process of dibutyl sulphide (DBS) electro-oxidation using electrolysis and cyclic voltamperometry was investigated in water-methanol solution using different electrodes (platinum, boron doped diamond, graphite and glassy carbon). Obtained results indicate that the DBS electro-oxidation process is irreversible in voltamperometric
Francisco Palacios et al.
The Journal of organic chemistry, 67(7), 2131-2135 (2002-04-02)
Functionalized keto-enamines 6 were obtained by nucleophilic addition of enol ethers to the imine moiety of 2-azadienes derived from dehydroaspartic esters 4. Reactions of 2-azadiene 4c containing three electron-withdrawing substituents (CO(2)R) with enol ethers 5 in the presence of lithium
Shokaku Kim et al.
Organic letters, 4(21), 3735-3737 (2002-10-12)
[reaction: see text] N-Acyliminium cation of prolines was efficiently generated to accumulate in an undivided cell at 0 degrees C by an anodic oxidation of N-acylprolines or alpha'-phenylsulfanylated N-acylproline derivatives in a lithium perchlorate/nitromethane solution. The iminium cation intermediates gave
L H Sim et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 76(3-4), 287-292 (2010-05-07)
The interaction behaviours between components of polyacrylate (PAc)/poly(ethylene oxide) (PEO) and lithium perchlorate (LiClO(4)) were investigated in detail by Attenuated Total Reflectance (ATR)-Fourier Transformed Infrared (FTIR) spectroscopy. Solution cast films of the PAc/PEO and PAc/PEO/LiClO(4) were examined. No obvious shifting
Natalia Varaksa et al.
Proceedings of the National Academy of Sciences of the United States of America, 99(8), 5012-5017 (2002-04-18)
The adsorption of the trigonal connector, 1,3,5-tris[10-(3-ethylthiopropyl)dimethylsilyl-1,10-dicarba-closo-decaboran-1-yl]benzene (1), from acetonitrile/0.1 M LiClO(4) on the surface of mercury at potentials ranging from +0.3 to -1.4 V (vs. aqueous Ag/AgCl/1 M LiCl) was examined by voltammetry, Langmuir isotherms at controlled potentials, and

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