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Merck
CN

01-5610

Sigma-Aldrich

苯胺

SAJ first grade, ≥99.0%

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About This Item

线性分子式:
C6H5NH2
CAS号:
分子量:
93.13
Beilstein:
605631
EC 号:
MDL编号:
UNSPSC代码:
12352106
PubChem化学物质编号:

等级

SAJ first grade

蒸汽密度

3.22 (185 °C, vs air)

蒸汽压

0.7 mmHg ( 25 °C)

方案

≥99.0%

表单

liquid

自燃温度

1139 °F

expl. lim.

11 %

存货情况

available only in Japan

折射率

n20/D 1.586 (lit.)

pH值(酸碱度)

8.8 (20 °C, 36 g/L)

沸点

184 °C (lit.)

mp

−6 °C (lit.)

密度

1.022 g/mL at 25 °C (lit.)

SMILES字符串

Nc1ccccc1

InChI

1S/C6H7N/c7-6-4-2-1-3-5-6/h1-5H,7H2

InChI key

PAYRUJLWNCNPSJ-UHFFFAOYSA-N

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生化/生理作用

苯胺的急性毒性涉及其在体内活化为4-羟基苯胺和与血红蛋白形成加合物。 在红细胞中,这与铁的释放和高铁血红蛋白的积累以及溶血性贫血和脾脏炎症的发展有关。长期给药时,在脾脏中常可观察到肿瘤形成。

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Muta. 2 - Skin Sens. 1 - STOT RE 1

靶器官

Blood

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

158.0 °F - closed cup

闪点(°C)

70 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

Lot/Batch Number

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A novel and efficient copper-catalyzed azidation reaction of anilines via C-H activation has been developed. This method, in which the primary amine acts as a directing group by coordinating to the metal center, provides ortho azidation products regioselectively under mild

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