8.53029
Boc-Glu(OcHx)-OH
Novabiochem®
别名:
Boc-Glu(OcHx)-OH, N-α-t.-Boc-L-glutamic acid γ-cyclohexyl ester
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关于此项目
经验公式（希尔记法）:
C16H27NO6
化学文摘社编号:
分子量:
329.39
MDL number:
UNSPSC Code:
12352209
NACRES:
NA.22
产品名称
Boc-Glu(OcHx)-OH, Novabiochem®
SMILES string
N([C@@H](CCC(=O)OC1CCCCC1)C(=O)O)C(=O)OC(C)(C)C
InChI
1S/C16H27NO6/c1-16(2,3)23-15(21)17-12(14(19)20)9-10-13(18)22-11-7-5-4-6-8-11/h11-12H,4-10H2,1-3H3,(H,17,21)(H,19,20)/t12-/m0/s1
InChI key
FDNMLANBNJDIRG-LBPRGKRZSA-N
product line
Novabiochem®
assay
≥98% (TLC)
form
powder
reaction suitability
reaction type: Boc solid-phase peptide synthesis
manufacturer/tradename
Novabiochem®
mp
54-57 °C
application(s)
peptide synthesis
functional group
carboxylic acid
storage temp.
2-30°C
Quality Level
Analysis Note
Colour (visual): white to slight yellow to beige
Appearance of substance (visual): powder
Identity (IR): passes test
Optical rotation α 25/D (c=1 in methanol): -9.0 - -7.0 °
Purity (TLC(0811)): ≥ 98 %
Purity (DC (0157)): ≥ 98 %
Solubility (1 mmole in 2 ml DMF): clearly soluble
To see the solvent systems used for TLC of Novabiochem® products please click here.
Appearance of substance (visual): powder
Identity (IR): passes test
Optical rotation α 25/D (c=1 in methanol): -9.0 - -7.0 °
Purity (TLC(0811)): ≥ 98 %
Purity (DC (0157)): ≥ 98 %
Solubility (1 mmole in 2 ml DMF): clearly soluble
To see the solvent systems used for TLC of Novabiochem® products please click here.
General description
Standard building block for introduction of glutamic acid in Boc SPPS. This side-chain protecting group for glutamic acid is used to minimize side reactions during acidic and basic treatments [1].
Associated Protocols and Technical Articles
Cleavage and Deprotection Protocols for Boc SPPS
Literature references
[1] J. P. Tam, et al. (1979) Tetrahedron Lett., 42, 4033.
Associated Protocols and Technical Articles
Cleavage and Deprotection Protocols for Boc SPPS
Literature references
[1] J. P. Tam, et al. (1979) Tetrahedron Lett., 42, 4033.
Other Notes
Replaces: 04-12-0121
Legal Information
Novabiochem is a registered trademark of Merck KGaA, Darmstadt, Germany
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
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实验方案
Anhydrous HF is the preferred reagent for peptide cleavage from Boc-based resins, versatile and effective for various peptide synthesis.
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