8.52216
Fmoc-Dpr(Boc-Aoa)-OH
Novabiochem®
别名:
Fmoc-Dpr(Boc-Aoa)-OH, N-α-Fmoc-N-β-(N-t.-Boc-amino-oxyacetyl)-L-diaminopropionic acid
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选择尺寸
关于此项目
经验公式（希尔记法）:
C25H29N3O8
化学文摘社编号:
分子量:
499.51
MDL number:
UNSPSC Code:
12352209
NACRES:
NA.22
产品名称
Fmoc-Dpr(Boc-Aoa)-OH, Novabiochem®
SMILES string
N(OCC(=O)NC[C@H](NC(=O)OCC1c2c(cccc2)c3c1cccc3)C(=O)O)C(=O)OC(C)(C)C
InChI
1S/C25H29N3O8/c1-25(2,3)36-24(33)28-35-14-21(29)26-12-20(22(30)31)27-23(32)34-13-19-17-10-6-4-8-15(17)16-9-5-7-11-18(16)19/h4-11,19-20H,12-14H2,1-3H3,(H,26,29)(H,27,32)(H,28,33)(H,30,31)/t20-/m0/s1
InChI key
KHRQNEDYPNTPKW-FQEVSTJZSA-N
product line
Novabiochem®
assay
≥95.0% (acidimetric)
≥96.0% (HPLC)
≥98% (TLC)
form
powder
reaction suitability
reagent type: ligand
manufacturer/tradename
Novabiochem®
application(s)
peptide synthesis
functional group
Boc
Fmoc
storage temp.
2-30°C
Quality Level
Analysis Note
Color (visual): white to slight yellow to beige
Appearance of substance (visual): powder
Identity (IR): passes test
Enantiomeric purity: ≥ 99.5 % (a/a)
Purity (TLC(CMA2)): ≥ 98 %
Assay (HPLC, area%): ≥ 96.0 % (a/a)
Solubility (1 mmole in 2 ml DMF): clearly soluble
Assay (acidimetric): ≥ 95.0 %
Water (K. F.): ≤ 2.00 %
To see the solvent systems used for TLC of Novabiochem® products please click here.
Appearance of substance (visual): powder
Identity (IR): passes test
Enantiomeric purity: ≥ 99.5 % (a/a)
Purity (TLC(CMA2)): ≥ 98 %
Assay (HPLC, area%): ≥ 96.0 % (a/a)
Solubility (1 mmole in 2 ml DMF): clearly soluble
Assay (acidimetric): ≥ 95.0 %
Water (K. F.): ≤ 2.00 %
To see the solvent systems used for TLC of Novabiochem® products please click here.
General description
An excellent derivative for the chemoselective ligation of unprotected peptides in aqueous media [1] via oxime formation. This derivative introduces a hydroxylamine functionality which can couple with aldehyde groups present in another peptide unit.
Associated Protocols and Technical Articles
Cleavage and Deprotection Protocols for Fmoc SPPS
Literature references
[1] F. Wahl & M. Mutter (1996) Tetrahedron Lett., 37, 6861.
Associated Protocols and Technical Articles
Cleavage and Deprotection Protocols for Fmoc SPPS
Literature references
[1] F. Wahl & M. Mutter (1996) Tetrahedron Lett., 37, 6861.
Other Notes
Replaces: 04-12-1185
Legal Information
Novabiochem is a registered trademark of Merck KGaA, Darmstadt, Germany
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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