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Merck
CN

8.43705

Sodium triacetoxyborohydride

for synthesis

别名:

Sodium triacetoxyborohydride

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关于此项目

经验公式（希尔记法）:
C6H10BNaO6
化学文摘社编号:
56553-60-7
分子量:
211.94
UNSPSC Code:
12352302
NACRES:
NA.22
MDL number:
MFCD00012211

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产品名称

Sodium triacetoxyborohydride, for synthesis

SMILES string

[Na+].[B-H](OC(=O)C)(OC(=O)C)OC(=O)C

InChI

1S/C6H10BO6.Na/c1-4(8)11-7(12-5(2)9)13-6(3)10;/h7H,1-3H3;/q-1;+1

InChI key

HHYFEYBWNZJVFQ-UHFFFAOYSA-N

form

powder

mp

110-114 °C

storage temp.

2-30°C

Quality Level

200

相关类别

Analysis Note

Assay (by gasvolumetry): ≥ 96.0 %
Identity (IR): passes test

Application

  • Chemical Synthesis: Used in the synthesis of (Piperazine-yl) Methanone derivatives with potential anticancer and antituberculosis activities, highlighting its role in facilitating N-alkylation reactions (Mallikarjuna et al., 2014).
  • Green Chemistry: Featured in the development of efficient N-methylation of secondary amines under solvent-free conditions, demonstrating its utility in sustainable chemical processes (Walter et al., 2024).
  • Organic Chemistry: Utilized in N-alkylation using carboxylic acids as alkyl sources, providing a versatile method for producing complex organic molecules (Tamura et al., 2018).

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Sol. 1 - Repr. 1B - Water-react 1

supp_hazards

EUH014

存储类别

4.3 - Hazardous materials, which set free flammable gases upon contact with water

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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Ken-Ichi Nakashima et al.
Journal of natural products, 82(12), 3347-3356 (2019-12-10)
Paraconiothins A-J (1-10), 10 new sesquiterpenoids, as well as five known sesquiterpenoids, were isolated from the cultures of the endophytic fungus Paraconiothyrium brasiliense ECN-258. The structures of the sesquiterpenoids were elucidated by extensive spectroscopic analysis. Furthermore, the absolute structures of

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