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经验公式(希尔记法):
Cl5P
化学文摘社编号:
分子量:
208.24
UNSPSC Code:
12352307
EC Index Number:
233-060-3
NACRES:
NA.22
MDL number:
产品名称
Phosphorus pentachloride, for synthesis
SMILES string
[P](Cl)(Cl)(Cl)(Cl)Cl
InChI
1S/Cl5P/c1-6(2,3,4)5
InChI key
UHZYTMXLRWXGPK-UHFFFAOYSA-N
vapor pressure
0.016 hPa ( 20 °C)
assay
≥99.0% (argenometric)
form
crystalline solid
potency
660 mg/kg LD50, oral (Rat)
pH
1 (5 g/L in H2O, acidic)
mp
148 °C
density
2.1 g/cm3 at 20 °C
storage temp.
2-30°C
Quality Level
Analysis Note
Assay (argentometric): ≥ 99.0 %
Application
- Phosphorylation of Glycoluryl Derivatives: New organoelement phosphorus derivatives synthesized using glycoluril and phosphorus pentachloride under controlled conditions (Salkeeva et al., 2021).
- Alcohol Amination and Cyclization: Catalyzed alcohol amination of diethanolamine by a Ru-PNP Pincer complex using phosphorus pentachloride to produce piperazine, demonstrating high conversion rates (van der Loo et al.).
- Chemical Weapons Convention Relevance: Rapid GC-MS screening of chlorides relevant to the Chemical Weapons Convention, including phosphorus pentachloride, for monitoring prohibited chemical activities (Kuitunen et al., 2020).
- Silicon Nanocrystal Functionalization: Phosphorus pentachloride used for the functionalization of silicon nanocrystals, enhancing their utility in advanced materials applications (Islam et al., 2017).
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Inhalation
target_organs
Respiratory Tract
supp_hazards
存储类别
6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 1
法规信息
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