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蒸汽压
12 hPa ( 20 °C)
质量水平
形式
liquid
效能
3160 mg/kg LD50, skin (Rabbit)
bp
136 °C/1013 hPa
mp
-24 °C
密度
1.728 g/cm3 at 20 °C
储存温度
2-30°C
InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
InChI key
XJDNKRIXUMDJCW-UHFFFAOYSA-J
应用
Titanium(IV) chloride can be used as a Lewis acid catalyst:
- In the ortho acylation of aryl alcohols to synthesize corresponding ortho C-acylated products.
- To synthesize various chlorinated compounds via Baylis−Hillman reaction reactions of aryl aldehydes with methyl vinyl ketone in the presence of Lewis base.
- To prepare 3,4-dihydropyrimidin-2(1H)-ones and thiones by Biginelli condensation reaction of aldehyde, 1,3-dicarbonyl compound, and urea or thiourea.
- In the hydrodefluorination reaction in the presence of triethylsilane as the reducing agent.
分析说明
Assay (argentometric): ≥ 97.0 %
Identity (ICP-OES): passes test
Identity (ICP-OES): passes test
警示用语：
Danger
危险分类
Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
补充剂危害
储存分类代码
6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
M Shi, et al.
Organic Letters, 2(16), 2397-2400 (2000)
Titanium (IV) chloride catalyzed one-pot synthesis of 3, 4-dihydropyrimidin-2 (1H)-ones and thiones
Nagawade RR, et al.
Mendeleev Communications, 15(4), 150-151 (2005)
Titanium (IV) chloride-mediated ortho-acylation of phenols and naphthols
Bensari A and Zaveri NT
Synthesis, 2003(02), 0267-0271 (2003)
Transformation of Trifluorotoluenes Triggered by Titanium (IV) Chloride-Catalyzed Hydrodefluorination using Hydrosilanes
Yamada T, et al.
advanced synthesis and catalysis, 358(1), 62-66 (2016)
Transformation of Trifluorotoluenes Triggered by Titanium (IV) Chloride-Catalyzed Hydrodefluorination using Hydrosilanes
Yamada T, et al.
Advanced Synthesis & Catalysis, 358(1), 62-66 (2016)
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