8.08913
氯化锆(IV)
anhydrous, for synthesis
别名:
氯化锆(IV)
登录 查看组织和合同定价。
选择尺寸
关于此项目
经验公式（希尔记法）:
Cl4Zr
化学文摘社编号:
分子量:
233.04
UNSPSC Code:
12352302
EC Index Number:
233-058-2
NACRES:
NA.22
MDL number:
Grade:
synthesis grade
Form:
crystals
产品名称
氯化锆(IV), anhydrous, for synthesis
SMILES string
[Zr](Cl)(Cl)(Cl)Cl
InChI
1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4
InChI key
DUNKXUFBGCUVQW-UHFFFAOYSA-J
grade
synthesis grade
vapor pressure
1.3 hPa ( 190 °C)
form
crystals
potency
1688 mg/kg LD50, oral (Rat)
Quality Level
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
pH
<1 (20 °C in H2O, saturated aqueous solution)
mp
437 °C
density
2.80 g/cm3 at 15 °C
bulk density
1200 kg/m3
greener alternative category
storage temp.
2-30°C
相关类别
Analysis Note
含量（银量法）： ≥ 98.0％
铪（Hf）： ≤ 40 ppm
同一性（ICP-OES）：通过测试
铪（Hf）： ≤ 40 ppm
同一性（ICP-OES）：通过测试
Application
氯化锆（IV）可用作催化剂，以：
- β通过环氧衍生物与芳香胺的开环反应合成氨基醇。
- 通过脂肪胺与α, β-不饱和酯、腈类和酮类的共轭加成合成β氨基酸类似物。
- 通过1,2-双酰肼的环化脱水作用合成1,3,4-恶二唑类化合物。
- 通过芳族醛、β-酮酯和尿素的Biginelli缩合反应合成3,4-二氢嘧啶衍生物。
General description
氯化锆（IV）是一种Lewis酸催化剂，广泛用于有机合成，以制备有用的关键中间体。基于其稳定性和环保性，这种催化剂适用于各种化学反应，比如碳-碳键形成反应、还原反应、保护反应和脱保护反应等。
Features and Benefits
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
signalword
Danger
hcodes
Hazard Classifications
Met. Corr. 1 - Skin Corr. 1B
supp_hazards
存储类别
8B - Non-combustible, corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
危险化学品
此项目有
Zirconium (IV) Chloride-Mediated Chemoselective Conjugate Addition of Aliphatic Amines to α, β-Ethylenic Compounds
Meshram HM, et al.
Synthetic Communications, 36(6), 795-801 (2006)
Zirconium (IV) chloride catalyzed one-pot synthesis of 3, 4-dihydropyrimidin-2 (1H)-ones
Reddy Ch Venkateshwar, et al.
Tetrahedron Letters, 43(14), 2657-2659 (2002)
Zirconium (IV) chloride catalyzed ring opening of epoxides with aromatic amines
Swamy NR, et al.
Synthetic Communications, 34(4), 727-734 (2004)
Zirconium (IV) Chloride Mediated Cyclodehydration of 1, 2-Diacylhydrazines: A Convenient Synthesis of 2, 5-Diaryl 1, 3, 4-Oxadiazoles
Sharma GVM, et al.
Synthetic Communications, 34(13), 2387-2391 (2004)
Applications of zirconium (IV) chloride in organic synthesis
Smitha G, et al.
Synthesis, 2008(06), 829-855 (2008)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持