蒸汽压
1.33 hPa ( 671 °C)
质量水平
形式
powder
效能
105 mg/kg LD50, oral (Rat)
pH值（酸碱度）
4 (20 °C, 500 g/L in H2O)
mp
1009 °C
密度
3.55 g/cm3
储存温度
2-30°C
InChI
1S/2ClH.Ni/h2*1H;/q;;+2/p-2
InChI key
QMMRZOWCJAIUJA-UHFFFAOYSA-L
应用
Nickel(II) chloride can be used as a catalyst:
- To synthesize acyclic and cyclic dithioacetals via thioacetalization of aldehydes.
- To prepare α-aminonitrile derivatives via a one-pot, three-component coupling reaction of aldehydes, amines, and trimethylsilyl cyanide.
- In the hydrodefluorination of fluoroarenes in the presence of lithium triethylborohydride.
分析说明
Assay (complexometric): 98.0 - 102.0 %
Loss on drying (150 °C; 3h): ≤ 1.0 %
Loss on drying (150 °C; 3h): ≤ 1.0 %
警示用语：
Danger
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation
靶器官
Lungs
储存分类代码
6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
Highly Efficient Nickel (II) Chloride/Bis (tricyclohexylphosphine) nickel (II) Chloride-Cocatalyzed Hydrodefluorination of Fluoroarenes and Trifluorotoluenes with Superhydride
Zhao Wenwen, et al.
Advanced Synthesis & Catalysis, 354(4), 574-578 (2012)
Nickel (II) chloride as an efficient and useful catalyst for chemoselective thioacetalization of aldehydes
Khan AT, et al.
Tetrahedron Letters, 44(5), 919-922 (2003)
Nickel (II) chloride catalyzed one-pot synthesis of α-aminonitriles
De Surya Kanta
J. Mol. Catal. A: Chem., 225(2), 169-171 (2005)
Highly Efficient Nickel (II) Chloride/Bis (tricyclohexylphosphine) nickel (II) Chloride-Cocatalyzed Hydrodefluorination of Fluoroarenes and Trifluorotoluenes with Superhydride
Zhao Wenwen, et al.
advanced synthesis and catalysis, 354(4), 574-578 (2012)
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