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Merck
CN
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主要文件

安全信息

8.03605

Sigma-Aldrich

Diethyl ketone

for synthesis

别名:

Diethyl ketone, 3-Pentanone, Ethyl ketone

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About This Item

线性分子式:
(C2H5)2CO
CAS号:
分子量:
86.13
MDL编号:
UNSPSC代码:
12352115
EC索引号:
202-490-3
NACRES:
NA.22
方案:
≥99% (GC)
沸点:
101-103 °C/1013 mbar
蒸汽压:
37.6 hPa ( 20 °C)

蒸汽压

37.6 hPa ( 20 °C)

质量水平

方案

≥99% (GC)

表单

liquid

自燃温度

425 °C

效能

2900 mg/kg LD50, oral (Rat)
16200 mg/kg LD50, skin (Rabbit)

expl. lim.

1.6-7.7 % (v/v)

pH值(酸碱度)

6.2 (20 °C, 50 g/L in H2O)

沸点

101-103 °C/1013 mbar

mp

-40 °C

转变温度

flash point 7 °C

溶解性

50 g/L

密度

0.81 g/cm3 at 20 °C

储存温度

2-30°C

SMILES字符串

O=C(CC)CC

InChI

1S/C5H10O/c1-3-5(6)4-2/h3-4H2,1-2H3

InChI key

FDPIMTJIUBPUKL-UHFFFAOYSA-N

应用


  • Resonance Stabilization Effects on Ketone Autoxidation: Isomer-Specific Cyclic Ether and Ketohydroperoxide Formation in the Low-Temperature (400-625 K) Oxidation of Diethyl Ketone.: This study examines the low-temperature oxidation of diethyl ketone, highlighting how resonance stabilization influences the formation of specific cyclic ethers and ketohydroperoxides, vital for understanding combustion mechanisms and environmental implications of ketone use in industrial applications (Scheer AM et al., 2016).

  • Low-temperature combustion chemistry of novel biofuels: resonance-stabilized QOOH in the oxidation of diethyl ketone.: This research focuses on the combustion chemistry of diethyl ketone as a biofuel, providing insights into the formation of resonance-stabilized QOOH intermediates which are crucial for developing more efficient and cleaner burning fuels (Scheer AM et al., 2014).

  • Wet effluent diffusion denuder technique and determination of volatile organic compounds in air. I. Oxo compounds (alcohols and ketones).: Explores the use of diethyl ketone in air quality monitoring, employing a novel wet effluent diffusion denuder technique for the sensitive detection of oxo compounds, vital for environmental monitoring and regulatory compliance (Pesková J et al., 2001).

  • Identification limits for volatile organic compounds in the blood by purge-and-trap GC-FTIR.: Discusses the detection limits of volatile organic compounds, including diethyl ketone, in blood using advanced purge-and-trap gas chromatography coupled with Fourier-transform infrared spectroscopy, emphasizing its importance in forensic and toxicological analyses (Ojanperä I et al., 1998).

分析说明

Assay (GC, area%): ≥ 99.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.813 - 0.815
Identity (IR): passes test

象形图

FlameExclamation mark

警示用语:

Danger

危险分类

Eye Irrit. 2 - Flam. Liq. 2

补充剂危害

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

44.6 °F

闪点(°C)

7 °C

法规信息

危险化学品

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