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等级
for synthesis
质量水平
蒸汽压
4.2 hPa ( 25 °C)
折射率
n20/D 1.449 (lit.)
bp
189 °C (lit.)
mp
<-60 °C
密度
1.042 g/mL at 25 °C (lit.)
1.07 g/cm3 at 25 °C
SMILES字符串
CC(=C)C(=O)OCC1CO1
InChI
1S/C7H10O3/c1-5(2)7(8)10-4-6-3-9-6/h6H,1,3-4H2,2H3
InChI key
VOZRXNHHFUQHIL-UHFFFAOYSA-N
一般描述
2,3-Epoxypropyl methacrylate is a methacrylic acid/glycidol ester. It is used as a monomer to produce polymers based on glycidyl methacrylate (GMA). It is also a dual functionality (epoxy and methacrylate) monomer, thus offering the opportunity for chemical modification of the parent polymer for various applications.
应用
2,3-Epoxypropyl methacrylate can be used as a monomer unit in polymer industries to produce poly (glycidyl methacrylate)(PGMA) for various uses in electronic and biomedical applications. The presence of epoxide group in PGMA allows it to be modified by a variety of functionalities such as amine-epoxy, thiol-epoxy, azide-epoxy, and acid-epoxy via nucleophilic ring-opening reactions. This overall flexibility in the functionalization of PGMA is because of the controlled polymerization of 2,3-epoxypropyl methacrylate monomer via free radical polymerization. Thus, PGMA is one of the most adaptable reactive scaffolds in polymer chemistry due to the long shelf life of the resulting polymers.
It is also used to prepare poly(n-butyl methacrylate-co-glycidyl methacrylate) copolymers, which find applications in adhesives, surface coatings, and electrical devices in various polymeric industries. The presence of epoxy groups and flexible butyl groups in epoxy resin-modified copolymers increases its mechanical properties, impact strength, and fracture elongation.
It is also used to prepare poly(n-butyl methacrylate-co-glycidyl methacrylate) copolymers, which find applications in adhesives, surface coatings, and electrical devices in various polymeric industries. The presence of epoxy groups and flexible butyl groups in epoxy resin-modified copolymers increases its mechanical properties, impact strength, and fracture elongation.
法律信息
Technipur is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Repr. 1B - Skin Corr. 1C - Skin Sens. 1 - STOT RE 1 - STOT SE 3
靶器官
Respiratory system
储存分类代码
6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
168.8 °F - closed cup
闪点(°C)
76 °C - closed cup
法规信息
新产品
Self-assembly and applications of poly(glycidyl methacrylate)s and their derivatives
Li Q-L, et al.
Chemical Communications (Cambridge, England), 87 (2014)
Diblock copolymers, triblock copolymers andmodel networks synthesized by sequential anionic polymerization of styrene and 2,3-epoxypropyl methacrylate
Hild G and Lamps J-P
Polymer, 39(12), 2637-2649 (1998)
Shi G, et al.
Polymer-Plastics Technology and Engineering, 54(9), 881-888 (2015)
Post-polymerization modification reactions of poly(glycidyl methacrylate)s
Muzammil EM, et al.
Royal Society of Chemistry Advances, 7, 55874-55884 (2017)
Epoxy-functional thermoplastic copolymers and their incorporation into a thermosetting resin
Sweet KR, et al.
Journal of Applied Polymer Science, 138(26), 50608-50608 (2021)
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