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Merck
CN
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1.13364

Sigma-Aldrich

四氢呋喃-d8

deuteration degree min 99.5% for NMR spectroscopy MagniSolv

别名:

Deuterated tetrahydrofuran, 氘代四氢呋喃

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About This Item

经验公式(希尔记法):
C4D8O
CAS号:
分子量:
80.16
Beilstein:
111854
MDL编号:
UNSPSC代码:
12142201
EC索引号:
216-898-4
NACRES:
NA.22

质量水平

形式

liquid

自燃温度

215 °C

效能

1650 mg/kg LD50, oral (Rat)

技术

NMR: suitable

杂质

≤0.030% Water (H<SUB>2</SUB>O) (NMR)
≤0.050% Water (H<SUB>2</SUB>O) (Karl Fischer)

折射率

n20/D 1.403 (lit.)

bp

65-66 °C (lit.)

mp

−106 °C (lit.)

转变温度

flash point -17.5 °C

密度

0.985 g/mL at 25 °C (lit.)

质量偏移

M+8

储存温度

2-8°C

SMILES字符串

[2H]C1([2H])OC([2H])([2H])C([2H])([2H])C1([2H])[2H]

InChI

1S/C4H8O/c1-2-4-5-3-1/h1-4H2/i1D2,2D2,3D2,4D2

InChI key

WYURNTSHIVDZCO-SVYQBANQSA-N

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一般描述

A wide range of MagniSolv deuterated solvents with extremely low residual water, excellent chemical purity, and the highest isotopic enrichment available can satisfy the most demanding requirements of researchers. Depending on application and sensitivity of the NMR spectrometer our offer solvents with deuteration degrees between 98% and 99.96%. In case of all the water soluble deuterated standard products, water content is specified according to both Karl Fischer and NMR.

应用


  • Experimental and Theoretical Study of CO2 Insertion into Ruthenium Hydride Complexes.: This research provides insights into the mechanistic pathways for CO2 reactivity with ruthenium hydride complexes, potentially relevant for catalytic applications including transformations involving Tetrahydrofuran-d₈ (Ramakrishnan et al., 2016).


  • Syntheses, structures, and NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds.: Details the synthesis and structural characterization of trimethyltin compounds, useful for understanding the coordination chemistry that may involve Tetrahydrofuran-d₈ as a solvent or structural analogue (Lichtscheidl et al., 2015).


  • NMR studies of coupled low- and high-barrier hydrogen bonds in pyridoxal-5′-phosphate model systems in polar solution.: Discusses the application of NMR spectroscopy in studying hydrogen bonding interactions, where Tetrahydrofuran-d₈ could be utilized as a deuterated solvent for enhanced spectral clarity (Sharif et al., 2007).


  • Stable hydrocarbon diradical, an analogue of trimethylenemethane.: Investigates stable hydrocarbon diradicals, where Tetrahydrofuran-d₈ may be used as part of the experimental setup to stabilize reactive intermediates or as a solvent to study radical stability (Rajca et al., 2005).


分析说明

Deuteration degree: ≥ 99.50 %
Water (NMR, H₂O): ≤ 0.030 %
Performance test (NMR-spectrum): passes test
Water (K. Fischer, H₂O + D₂O): ≤ 0.050 %

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法律信息

MAGNISOLV is a trademark of Merck KGaA, Darmstadt, Germany

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2

补充剂危害

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

1.4 °F - closed cup

闪点(°C)

-17 °C - closed cup


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