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Merck
CN
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安全信息

1.01245

Sigma-Aldrich

Isopentyl nitrite

extra pure stabilized with potassium carbonate

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别名:
Isopentyl nitrite, iso-Amyl nitrite, iso-Pentyl nitrite, Nitrous acid isoamyl ester
经验公式(希尔记法):
C5H11NO2
CAS号:
分子量:
117.15
MDL编号:
UNSPSC代码:
12352108
EC索引号:
203-770-8
NACRES:
NA.22

质量水平

形式

liquid

自燃温度

208 °C

效能

505 mg/kg LD50, oral (Rat)

bp

97-99 °C/1013 hPa

转变温度

flash point -18 °C

密度

0.872 g/cm3 at 20 °C

储存温度

2-8°C

InChI

1S/C5H11NO2/c1-5(2)3-4-8-6-7/h5H,3-4H2,1-2H3

InChI key

OWFXIOWLTKNBAP-UHFFFAOYSA-N

应用

  • Deaminative coupling of benzylamines and arylboronic acids: Research demonstrated the use of isopentyl nitrite in the deaminative coupling of benzylamines and arylboronic acids, showcasing its application in creating complex molecules for pharmaceutical and chemical manufacturing processes (Sirvinskaite, Reisenbauer, and Morandi, 2023).
  • Syntheses of Arylazo Phosphine Oxides and Phosphonates: Utilizing isopentyl nitrite, research facilitated the synthesis of arylazo phosphine oxides and phosphonates via N-P bond formation under blue LED light conditions, contributing to developments in organophosphorus chemistry (Shen et al., 2022).

分析说明

Total nitrites (GC): ≥ 97.0 % (a/a)
Identity (IR-spectrum): conforms
Free acid: conforms
Density (d 20 °C/ 4 °C): 0.8720 - 0.8770
Non volatile matter: ≤ 0.04 %

警示用语:

Danger

危险分类

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

-4.0 °F - closed cup

闪点(°C)

-20 °C - closed cup

法规信息

危险化学品

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