X1202
间苯二甲胺
99%
别名:
1,3-苯二甲胺, m-XDA, 1,3-二(氨甲基)苯, α,α′-二氨基间二甲苯
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关于此项目
线性分子式:
C6H4(CH2NH2)2
化学文摘社编号:
分子量:
136.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-032-5
Beilstein/REAXYS Number:
1099911
MDL number:
Assay:
99%
InChI key
FDLQZKYLHJJBHD-UHFFFAOYSA-N
InChI
1S/C8H12N2/c9-5-7-2-1-3-8(4-7)6-10/h1-4H,5-6,9-10H2
SMILES string
NCc1cccc(CN)c1
vapor pressure
15 mmHg ( 145 °C)
assay
99%
refractive index
n20/D 1.571 (lit.)
bp
265 °C/745 mmHg (lit.)
density
1.032 g/mL at 25 °C (lit.)
Quality Level
Application
间苯二甲胺可用于：
- 作为聚(乙烯基-氨基甲酸乙酯)类玻璃高分子(vitrimer)的合成单体。
- 作为氨基甲酸酯保护多取代双胍合成的起始材料。
- 通过二醇的催化脱氢反应合成聚酰胺。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Vinylogous urethane vitrimers.
Denissen W, et al.
Advances in Functional Materials, 25(16), 2451-2457 (2015)
Direct synthesis of polyamides via catalytic dehydrogenation of diols and diamines.
Zeng H and Guan Z
Journal of the American Chemical Society, 133(5), 1159-1161 (2011)
A versatile one-pot synthesis of 1, 3-substituted guanidines from carbamoyl isothiocyanates.
Linton BR, et al.
The Journal of Organic Chemistry, 65(5), 1566-1568 (2000)
Occupational contact dermatitis due to the epoxy hardener m-xylylenediamine.
S Sommer et al.
Contact dermatitis, 44(6), 374-374 (2001-06-22)
Yongmei Zhao et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(25), 6621-6629 (2006-06-07)
Polynuclear copper complexes with two or three Cu(BPA) (BPA, bis(2-pyridylmethyl)amine) motifs, [Cu2(mTPXA)Cl4]3 H2O (1), [Cu2(pTPXA)Cl4]3 H2O (2), [Cu3(HPTAB)Cl5]Cl3 H2O (3) (mTPXA = N,N,N',N'-tetra-(2-pyridylmethyl)-m-xylylene diamine; pTPXA = N,N, N',N'-tetra-(2-pyridylmethyl)-p-xylylenediamine; HPTAB = N,N,N',N',N'',N''-hexakis(2-pyridylmethyl)-1,3,5-tris-(aminomethyl)benzene) have been synthesized and characterized. The crystal structures of
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