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Merck
CN

W519103

Sigma-Aldrich

甲酸甲酯

≥95%

别名:

蚁酸甲酯

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About This Item

线性分子式:
HCO2CH3
CAS号:
分子量:
60.05
Beilstein:
1734623
EC 号:
MDL编号:
UNSPSC代码:
12164502
PubChem化学物质编号:
Flavis编号:
9.642
NACRES:
NA.21
方案:
≥95%
应用:
flavors and fragrances
沸点:
32-34 °C (lit.)

生物来源

synthetic

蒸汽密度

2.1 (vs air)

方案

≥95%

表单

liquid

自燃温度

842 °F

expl. lim.

23 %

折射率

n20/D 1.343 (lit.)

pH值(酸碱度)

4.0-5.0 (20 °C, 200 g/L)

沸点

32-34 °C (lit.)

mp

−100 °C (lit.)

密度

0.974 g/mL at 20 °C (lit.)

应用

flavors and fragrances

文件

see Safety & Documentation for available documents

食品过敏原

no known allergens

性状检查

fruity; plum

SMILES字符串

[H]C(=O)OC

InChI

1S/C2H4O2/c1-4-2-3/h2H,1H3

InChI key

TZIHFWKZFHZASV-UHFFFAOYSA-N

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一般描述

Methyl formate finds application as a fumigant in raisins and dried currants.

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

-2.2 °F - closed cup

闪点(°C)

-19 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Winter R
A Consumer's Dictionary of Food Additives, 352-352 null
T Sethre et al.
International archives of occupational and environmental health, 73(6), 401-409 (2000-09-28)
The aim of the study was to investigate the acute effects of experimental methylformate exposure on the nervous system. In an exposure chamber, 20 subjects were exposed to methylformate at 100 ppm [Swiss maximum allowable concentration (MAC)] for 8 h.
Wayne K Metcalfe et al.
The journal of physical chemistry. A, 114(17), 5478-5484 (2010-04-13)
The energetics and kinetics of methyl formate decomposition have been investigated by high-level ab initio calculations with rate constant predictions. The paucity of reliable experimental data for methyl formate has been circumvented by studying a very similar system, namely, the
Ivan Cornella et al.
The Journal of organic chemistry, 69(6), 2191-2193 (2004-04-03)
A total synthesis following the sequence in Scheme 1 confirms that porritoxin possesses revised structure 3, not the originally assigned 1. A key reaction was the use of iron pentacarbonyl to formylate an aryllithium when DMF and methyl formate proved
Kristin Skinner et al.
Applied and environmental microbiology, 75(17), 5514-5522 (2009-07-08)
The filamentous fungus Graphium sp. (ATCC 58400) grows on gaseous n-alkanes and diethyl ether. n-Alkane-grown mycelia of this strain also cometabolically oxidize the gasoline oxygenate methyl tert-butyl ether (MTBE). In this study, we characterized the ability of this fungus to

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