质量水平
检测方案
98%
mp
116-118 °C (lit.)
SMILES字符串
OCC(C(O)=O)c1ccccc1
InChI
1S/C9H10O3/c10-6-8(9(11)12)7-4-2-1-3-5-7/h1-5,8,10H,6H2,(H,11,12)
InChI key
JACRWUWPXAESPB-UHFFFAOYSA-N
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应用
托品酸可作为下列反应的底物：
- Dowex H+/NaI催化系统下的羧酸和醇的酯化反应。
- 环戊酯肽的多步合成反应。
- 与四氰苯(TCNB)通过多组分光化学反应合成异香豆素衍生物。
托品酸用于合成 (-)-樟柳碱 、阿托品和莨菪碱。
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Photo-multicomponent reactions leading to the construction of isocoumarins and large ring lactone precursors
Lu Z, et al.
Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society for Photobiology, 8(2), 217-223 (2009)
Tropane alkaloids in pharmaceutical and phytochemical analysis.
Gadzikowska, MARIA and Grynkiewicz, GRZEGORZ
Acta Poloniae Pharmaceutica, 59(2), 149-160 (2002)
Green and Efficient Esterification Method Using Dried Dowex H+/NaI Approach
Turhanen PA, et al.
ACS Omega, 4(5), 8974-8984 (2019)
Synthesis of conformationally restricted cyclic pentadepsipeptides via direct amide cyclization
Koch KN, et al.
Tetrahedron, 57(12), 2311-2326 (2001)
Junbiao Chang et al.
European journal of medicinal chemistry, 41(3), 397-400 (2006-01-18)
-Anisodine (l-6,7-epoxy-3-tropyl-alpha-hydroxytropate), which was isolated from the medicinal plant Scopolia tanguticus Maxim, was the first efficiently prepared using 6-beta-acetyltropine as the starting material via a key step of the Sharpless asymmetric dihydroxylation (AD). The intermediate compounds 10 and 11 showed
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