T8809
四氰乙烯
96%
别名:
NSC 24833, TCNE, 四氰基乙烯, 四氰基代乙烯
登录 查看组织和合同定价。
选择尺寸
关于此项目
线性分子式:
(NC)2C=C(CN)2
化学文摘社编号:
分子量:
128.09
UNSPSC Code:
12352117
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-578-0
Beilstein/REAXYS Number:
1679885
MDL number:
Assay:
96%
InChI key
NLDYACGHTUPAQU-UHFFFAOYSA-N
InChI
1S/C6N4/c7-1-5(2-8)6(3-9)4-10
SMILES string
N#CC(C#N)=C(C#N)C#N
assay
96%
reaction suitability
reagent type: oxidant
mp
197-199 °C (lit.)
storage temp.
2-8°C
Quality Level
Application
用于聚苯乙炔衍生物的后官能化加成，以改变透氧性
作为以下反应的反应物：
作为以下反应的反应物：
- 区域选择性[2+2]环加成反应，用于生产BODIPY染料 和TCBD衍生物
- 与炔的热力加成反应
- 与亲核试剂的一锅法反应，形成芳香族氰基乙烯基化合物
- 合成四氰乙烯钴薄膜
- 通过灰霉菌（Botrytis cinerea）进行生物转化
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Oral - Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Gerasimos S Armatas et al.
Journal of the American Chemical Society, 130(34), 11430-11436 (2008-08-06)
We report the surfactant-directed assembly of mesoporous metal/germanium-based semiconducting materials from coupling of anionic (Ge 9) (4-) clusters with various linking metal ions. The resulting materials feature a metal/Ge 9 framework perforated by regular arrays of mesoporous channels. The permanent
Milan Kivala et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(25), 7638-7647 (2008-07-22)
A series of monomeric and oligomeric donor-substituted 1,1,4,4-tetracyanobuta-1,3-dienes (TCBDs) with various topologies have been synthesized by means of thermal [2+2] cycloaddition between tetracyanoethylene (TCNE) and donor-substituted alkynes, followed by retro-electrocyclization. One-electron-reduced and -oxidized stages of the donor-substituted TCBDs were generated
Matthew Mudge et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 15(17), 3776-3781 (2014-09-13)
The crystal structure of pentamethylbenzene has been obtained for the first time with the use of synchrotron radiation, whilst the low-energy spectrum of lattice dynamics, dominated by the methyl group torsions, was obtained using inelastic neutron scattering. The effect of
Siham Y Alqaradawi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 71(4), 1594-1598 (2008-08-12)
The solid charge-transfer complexes formed in the reaction of the electron donor 1,4,7-trimethyl-1,4,7-triazacyclononane (TMTACN) with the acceptors iodine, tetracyanoethylene (TCNE) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) have been isolated. These were characterized through electronic and infrared spectra as well as thermal and elemental
Dane Tomasino et al.
The Journal of chemical physics, 138(9), 094506-094506 (2013-03-15)
We have studied the pressure-induced physical and chemical transformations of tetracyanoethylene (TCNE or C6N4) in diamond anvil cells using micro-Raman spectroscopy, laser-heating, emission spectroscopy, and synchrotron x-ray diffraction. The results indicate that TCNE in a quasi-hydrostatic condition undergoes a shear-induced
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持