T87807
三(羟甲基)乙烷
≥98%
别名:
2-羟甲基-2-甲基-1,3-丙二醇, 三羟甲基乙烷
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关于此项目
线性分子式:
CH3C(CH2OH)3
化学文摘社编号:
分子量:
120.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-063-9
Beilstein/REAXYS Number:
1304452
MDL number:
产品名称
三(羟甲基)乙烷, ≥98%
InChI key
QXJQHYBHAIHNGG-UHFFFAOYSA-N
InChI
1S/C5H12O3/c1-5(2-6,3-7)4-8/h6-8H,2-4H2,1H3
SMILES string
CC(CO)(CO)CO
assay
≥98%
mp
193-195 °C (lit.)
Quality Level
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Application
1,1,1-三（羟甲基）乙烷可用作合成以下物质的反应物：
它还可用作以下反应中的三齿 O-供体配体：
- 通过与脂肪族二羧酸二甲酯的缩聚反应制备的超支化聚酯。
- 通过与长链α-溴脂肪酸反应制备的三聚阴离子表面活性剂。
它还可用作以下反应中的三齿 O-供体配体：
- 芳基碘化物与酰胺、硫醇和酚之间的铜催化交叉偶联反应，用于通过形成 C−N、C−S 和 C−O 键制备相应的产物。
- 以铜催化剂和芳基碘进行氮杂杂环的N芳基化。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
320.0 °F - closed cup
flash_point_c
160.00 °C - closed cup
ppe
Eyeshields, Gloves, type N95 (US)
Biodegradable hyperbranched polyesters derived from 1, 1, 1-tris (hydroxymethyl) ethane
Kricheldorf HR and Behnken G
Journal of Polymer Science Part A: Polymer Chemistry, 47(1), 231-238 (2009)
Highly Efficient CuI-Catalyzed N-Arylation of Azaheterocycles with Aryl Iodides Using 1, 1, 1-Tris (Hydroxymethyl) ethane as a Tridentate O-Donor Ligand: A Shorter Route to Toloxatone and Formal Synthesis of Linezolid
Chen H-H, et al.
J. Chin. Chem. Soc., 57(1), 14-18 (2010)
1, 1, 1-Tris (hydroxymethyl) ethane as a new, efficient, and versatile tripod ligand for copper-catalyzed cross-coupling reactions of aryl iodides with amides, thiols, and phenols
Chen Y-J and Chen H-H
Organic Letters, 8(24), 5609-5612 (2006)
Synthesis and surface-active properties of a homologous series of star-like triple-chain anionic surfactants derived from 1, 1, 1-tris (hydroxymethyl) ethane
Li Xu, et al.
Journal of Surfactants and Detergents, 19(1), 129-135 (2016)
Eunmi Hong et al.
International journal of pharmaceutics, 574, 118893-118893 (2019-11-26)
Combination therapy, a treatment regimen that combines more than two therapeutic agents to diseased tissues has recently gained increasing attentions in anticancer therapy. As cancer cells are more vulnerable to oxidative stress and heat compared to normal cells, we developed
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