推荐产品
质量水平
检测方案
≥98%
mp
193-195 °C (lit.)
SMILES字符串
CC(CO)(CO)CO
InChI
1S/C5H12O3/c1-5(2-6,3-7)4-8/h6-8H,2-4H2,1H3
InChI key
QXJQHYBHAIHNGG-UHFFFAOYSA-N
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应用
1,1,1-三（羟甲基）乙烷可用作合成以下物质的反应物：
它还可用作以下反应中的三齿 O-供体配体：
- 通过与脂肪族二羧酸二甲酯的缩聚反应制备的超支化聚酯。
- 通过与长链α-溴脂肪酸反应制备的三聚阴离子表面活性剂。
它还可用作以下反应中的三齿 O-供体配体：
- 芳基碘化物与酰胺、硫醇和酚之间的铜催化交叉偶联反应，用于通过形成 C−N、C−S 和 C−O 键制备相应的产物。
- 以铜催化剂和芳基碘进行氮杂杂环的N芳基化。
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Gloves, type N95 (US)
Highly Efficient CuI-Catalyzed N-Arylation of Azaheterocycles with Aryl Iodides Using 1, 1, 1-Tris (Hydroxymethyl) ethane as a Tridentate O-Donor Ligand: A Shorter Route to Toloxatone and Formal Synthesis of Linezolid
Chen H-H, et al.
J. Chin. Chem. Soc., 57(1), 14-18 (2010)
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International journal of pharmaceutics, 574, 118893-118893 (2019-11-26)
Combination therapy, a treatment regimen that combines more than two therapeutic agents to diseased tissues has recently gained increasing attentions in anticancer therapy. As cancer cells are more vulnerable to oxidative stress and heat compared to normal cells, we developed
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Li Xu, et al.
Journal of Surfactants and Detergents, 19(1), 129-135 (2016)
1, 1, 1-Tris (hydroxymethyl) ethane as a new, efficient, and versatile tripod ligand for copper-catalyzed cross-coupling reactions of aryl iodides with amides, thiols, and phenols
Chen Y-J and Chen H-H
Organic Letters, 8(24), 5609-5612 (2006)
Biodegradable hyperbranched polyesters derived from 1, 1, 1-tris (hydroxymethyl) ethane
Kricheldorf HR and Behnken G
Journal of Polymer Science Part A: Polymer Chemistry, 47(1), 231-238 (2009)
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